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Potassium Bromide: Iron Bromide and Potash
Charlie

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Charlie

18. 十月 2026DE
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Potassium Bromide: Iron Bromide and Potash

Potassium bromide is the bromide of photography. Thorpe (1913): iron bromide solution run into hot potash solution until it is just neutral throws down the iron as oxide and leaves potassium bromide in solution, which is filtered, evaporated and crystallised. 100 parts of iron bromide take 56 to 60 parts of potash. The picture: potassium bromide crystals (Wikimedia Commons).
中级
2 days

说明

1

Make the two solutions

Dissolve the iron bromide in water and filter it. Dissolve 56 to 60 g of potash, according to its purity, in a little water and heat it.

此步骤所需材料:

溴化铁溴化铁100 克
碳酸钾(草木灰碱)碳酸钾(草木灰碱)60 克

所需工具:

水水
粗棉滤布粗棉滤布
铸铁锅铸铁锅
等臂天平等臂天平
2

Run the iron bromide into the potash

Pour the iron bromide solution into the hot potash until the liquid is exactly neutral or very faintly alkaline. Iron oxide falls out.

所需工具:

铸铁锅铸铁锅
石蕊试纸石蕊试纸
橡胶手套橡胶手套
3

Boil and filter

Boil for some time so the iron oxide settles dense, then filter it off.

所需工具:

铸铁锅铸铁锅
粗棉滤布粗棉滤布
4

Dry, then dissolve again

Evaporate to dryness. Dissolve the residue again in water: potassium sulphate and other dirt stay behind. Filter.

所需工具:

铸铁锅铸铁锅
水水
粗棉滤布粗棉滤布
5

Crystallise

Boil down to specific gravity 1.53, then evaporate further at a gentle heat in a stoneware or enamelled dish, for hard crystals.

所需工具:

铸铁锅铸铁锅
比重计比重计
蒸发皿蒸发皿
6

Dry at 40 to 50 °C

Dry the crystals at 40 to 50 °C, not above, or they crackle and burst.

所需工具:

蒸发皿蒸发皿
温度计温度计

材料

2

所需工具

9

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