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Petroleum Coke: Crude Oil Residue Coked in a Delayed Coker and Calcined
Petroleum coke is the solid carbon left from the heaviest part of crude oil. A refinery distils crude oil, then distils the residue again under vacuum, heats what is still left to about 480–505 °C and lets it crack in a coke drum. The drum fills with green coke in 12 to 24 hours; it is cut out with a water jet and calcined in a rotary kiln. Calcined coke feeds synthetic graphite and carbon anodes.
The picture: our diagram of the route from crude oil to calcined coke.
Avancé
A day per coke drum
Consignes
1
1
Distil the crude oil
Distil the crude oil
Distil crude oil in an atmospheric column, slightly above atmospheric pressure. Draw off the lighter cuts, among them naphtha (boiling between about 30 and 200 °C), and keep the residue from the bottom, which boils above 370–380 °C.
Matériaux pour cette étape :
Pétrole brut1 tOutils nécessaires :
Colonne de distillation atmosphérique2
2
Distil the residue under vacuum
Distil the residue under vacuum
Distil that residue again at 10–40 mmHg absolute so it stays below 370–380 °C. The heavy bottoms left are the vacuum residue.
Outils nécessaires :
Colonne de distillation sous vide
Pompe à vide3
3
Heat and fill the coke drum
Heat and fill the coke drum
Pump the vacuum residue through the coker furnace to about 480–505 °C, with steam in the tubes, into a coke drum. It cracks there: gas oil and lighter parts leave as vapour and coke builds up in the drum, which fills in 12 to 24 hours.
Outils nécessaires :
Unité de cokéfaction retardée
Eau4
4
Quench and cut out
Quench and cut out
Switch the feed to the second drum. Steam out the full drum, fill it with water, wait several hours and drain it. Cut the coke out with a high-pressure water jet. This is green coke.
Outils nécessaires :
Unité de cokéfaction retardéeEau5
5
Calcine
Calcine
Calcine the green coke in a rotary kiln at about 1300 °C to drive off the remaining volatile hydrocarbons.
Outils nécessaires :
Four rotatif6
6
Coke from a tonne of residue
Coke from a tonne of residue
Chargement du notebook Jupyter…
Matériaux
1- 1 tEspace réservé
Outils requis
6- Espace réservé
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