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Neodymium Magnets, Sample 7: 77Fe-8B-15Nd Sintered (Sagawa 1988)
Neodymium magnets are iron, boron and neodymium. Sagawa's team at Sumitomo melted the three together, ground the casting to a powder finer than 10 µm, lined the grains up in a magnetic field while pressing them, and sintered the compact in argon. This is their sample 7, 77 % iron, 8 % boron and 15 % neodymium by atoms: 32.1 MGOe.
Source: M. Sagawa et al. (Sumitomo Special Metals), US 4,770,723 (1988). Unknown: how the pure iron, the ferroboron and the neodymium metal are made, and how the finished magnets are magnetised; the patent does not say. The 1 kg weights are our arithmetic from the patent's atomic percentages. Picture: the patent's Fig. 8.
Ahli
2 days
Instruksi
1
1
Weigh sample 7: 77 Fe, 8 B, 15 Nd
Weigh sample 7: 77 Fe, 8 B, 15 Nd
Sample 7 is 77 % iron, 8 % boron and 15 % neodymium by atoms. Use 99.9 % electrolytic iron, ferroboron (19.38 % B, 5.32 % Al, 0.74 % Si, 0.03 % C, the rest iron) and neodymium of 99.7 % or better. Ours: a 1 kg melt, by arithmetic: 605.7 g iron, 68.1 g ferroboron, 330.3 g neodymium. Unknown: how these three are made.
Material untuk langkah ini:
Besi elektrolitik605.7 g
Ferroboron68.1 g
Logam neodimium330.3 gAlat yang dibutuhkan:
Neraca lengan2
2
Melt by high frequency in argon and cast
Melt by high frequency in argon and cast
Melt the charge in a high-frequency (induction) furnace under argon and pour it into a water-cooled copper mould.
Alat yang dibutuhkan:
Tanur induksi
Kowi Tanah Liat Tahan Api
Argon
Tabung gas bertekanan
Cetakan tembaga berpendingin air
Sarung Tangan Tahan Panas3
3
Stamp to 35 mesh, ball-mill to 3-10 µm
Stamp to 35 mesh, ball-mill to 3-10 µm
Crush the casting in a stamp mill until it passes a 35-mesh sieve. Then grind it in a ball mill for 3 hours, to 3-10 µm.
Alat yang dibutuhkan:
Penumbuk Bijih
Set ayakan (mata bertingkat)
Ball Mill Besi
Kacamata pengaman4
4
Press in a 10 kOe field at 1.5 t/cm²
Press in a 10 kOe field at 1.5 t/cm²
Line the powder up in a magnetic field of 10 kOe and press it at 1.5 tonnes per cm². Unknown: the size and shape of the magnets.
Alat yang dibutuhkan:
Pres medan magnet5
5
Sinter in argon at 1000-1200 °C
Sinter in argon at 1000-1200 °C
Sinter the compacts at 1000-1200 °C for about one hour in argon, then let them cool. Sample 7 measured 12.1 kG remanence, 7.3 kOe coercivity and 32.1 MGOe.
Alat yang dibutuhkan:
Tungku Tabung
Argon
Tabung gas bertekanan
Sarung Tangan Tahan Panas6
6
Magnetise the magnets
Magnetise the magnets
Unknown: how the sintered magnets are magnetised. Sagawa measures them on a B-H tracer but gives no magnetising field or apparatus.
Alat yang dibutuhkan:
Metode magnetisasi tak diketahuiBahan
3- 605.7 gPlaceholder
- 68.1 gPlaceholder
- 330.3 gPlaceholder
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