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Tannic Acid: Chinese Galls Extracted with Warm Water, Shaken with Ether and Dried on Tin Sheets
This is the large-scale way to make commercial tannin, as Thorpe's Dictionary (1913) gives it. Chinese galls from sumach hold as much as 70 % tannin; the best oak galls, from Aleppo, 50–60 %. The powder is extracted with warm water, and the extract is shaken with ether. After several days the ether layer on top is taken off; the tannin stays in the lower layer, which is dried on hot tin sheets until it puffs up. The product still holds some gallic acid, wax and glucose. Ether is very flammable: no flame.
The picture: our diagram.
Menengah
1 week
Instruksi
1
1
Extract the powdered galls with warm water
Extract the powdered galls with warm water
Powder Chinese galls finely. Stir with enough water at 50–60 °C to make a strong extract. Filter it clear.
Material untuk langkah ini:
Gall Tiongkok1 as requiredAlat yang dibutuhkan:
Air
Lumpang dan Alu Batu
Pengaduk
Penangas Air
Termometer Laboratorium
Kertas Saring
Corong Kaca Bertangkai2
2
Shake with a quarter volume of ether
Shake with a quarter volume of ether
Add ether, one quarter of the extract's volume, and agitate until it forms an emulsion. Let it stand for several days.
Alat yang dibutuhkan:
Dietil Eter
Corong pisah berkeran
Lemari asam (bersaluran buang)
Kacamata Pelindung Cipratan Kimia
Sarung tangan karet3
3
Take off the ether layer and recover the ether
Take off the ether layer and recover the ether
Remove the upper ether layer. Run the lower layer, which holds all the tannin, into a still and distil off the ether in it to recover it. No flame near the ether.
Alat yang dibutuhkan:
Corong pisah berkeran
Alembik tembaga
Lemari asam (bersaluran buang)4
4
Dry on tin sheets over a steam coil
Dry on tin sheets over a steam coil
Let the syrupy liquid cool, spread it on tin sheets and heat them with a steam coil. The tannin quickly puffs up and dries.
Alat yang dibutuhkan:
Lembaran pelat timah
Koil Uap
Ketel uap
Sarung tangan karetBahan
1- 1 as requiredPlaceholder
Alat yang Diperlukan
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