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Reverse Osmosis: Pushing Water Uphill Through a Membrane
The solar still and the alembic both separate salt from water by evaporating the water — and both pay the latent heat of vaporisation to do it, about 2,400 kilojoules for every kilogram. That energy bill is why distillation stayed expensive for three thousand years.
Reverse osmosis does the same separation without a phase change. Osmosis drives fresh water INTO brine through a membrane that passes water and rejects salt; push back harder than that osmotic pressure and the flow reverses, leaving the salt behind. The idea was old, but it was useless until Sidney Loeb and Srinivasa Sourirajan at UCLA made a cellulose acetate film in 1959 with a dense skin a fraction of a micrometre thick on a porous backing — thin enough to pass useful water, sound enough to hold back the salt (US 3,133,132). Every desalination plant since descends from that film.
上級者
1 day
手順
1
1
Understand what you are pushing against
Understand what you are pushing against
Osmotic pressure is not friction and it is not the membrane resisting you. It is the pressure the salt solution would pull water in with, and you must exceed it before a single drop crosses the other way.
For sea water at 35 grams per litre that is about 27 bar. For the brackish water most small systems treat, a few bar. This one number decides whether your build is a bicycle pump or an industrial plant, and the notebook later works it out for your own water.
このステップの材料:
塩35 g必要な工具:
デジタルスケール
メスシリンダー2
2
Get a membrane and treat it gently
Get a membrane and treat it gently
Use a small domestic RO element — the kind sold for under-sink filters. Note which way round it runs: feed in, permeate out of the centre tube, concentrate out of the far end.
Two things kill a membrane quickly. Chlorine destroys polyamide film in hours, so anything chlorinated must go through carbon first — and note the irony, because the previous rung in this batch was about deliberately adding chlorine. And letting it dry out permanently collapses the pore structure: a membrane that has dried never recovers its flux.
必要な工具:
逆浸透膜3
3
Build the pressure side
Build the pressure side
Plumb a feed vessel to the membrane through a pump with a gauge in the line, and lead two outlets away: permeate to one jar, concentrate to another through a restrictor.
You need BOTH outlets flowing. A membrane run with the concentrate closed off becomes a dead end where salt piles up against the film — concentration polarisation — and the local osmotic pressure climbs until flow stops and scale forms. Every RO system in the world throws away a stream of concentrate; that is not waste, it is what carries the rejected salt out.
このステップの材料:
シリコンチューブ3 metre必要な工具:
自転車用フロアポンプ
圧力計4
4
Make brackish water and run it
Make brackish water and run it
Dissolve 2 grams of salt per litre — brackish, not sea — and run it through at increasing pressure while you watch the permeate outlet.
Below the osmotic pressure, nothing comes out. Cross it and permeate starts, slowly at first and then rising roughly in step with how far past it you push. Seeing that threshold with your own gauge is the whole point of building this: it is the moment an abstract equation becomes a thing you did with a pump.
このステップの材料:
塩20 g
蒸留水10 リットル必要な工具:
圧力計メスシリンダー
ストップウォッチ5
5
Rejection, flux and the energy bill
Rejection, flux and the energy bill
Jupyter ノートブックを読み込み中…
必要な工具:
メスシリンダーストップウォッチ6
6
Taste, test, and notice what is missing
Taste, test, and notice what is missing
Compare feed, permeate and concentrate. The permeate should read near neutral and taste flat; the concentrate should be noticeably saltier than what you started with, because the salt has to go somewhere.
RO strips almost everything — salts, metals, most organics, and microbes, which are enormous compared to the pores. That completeness is also the criticism: it removes the calcium and magnesium the body uses, which is why large plants remineralise afterwards rather than delivering the pure product.
必要な工具:
pH 試験紙
ガラス瓶7
7
Flush it, and never let it dry
Flush it, and never let it dry
Flush with clean water at low pressure for a few minutes after every run, to wash the concentrated layer off the film before it can crystallise.
For storage, keep the element wet and cool. If you will not use it for weeks, store it in the preservative solution it came in. A dried-out membrane looks identical to a working one, and behaves like a blank sheet of plastic — the most expensive way there is to learn this lesson.
このステップの材料:
蒸留水5 リットル必要な工具:
自転車用フロアポンプ関連ブループリント
これらのブループリントは知識を共有しています — 技術、材料、原理
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