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Styrene: Ethylbenzene and Steam over a Magnesia-Iron Oxide Catalyst
Styrene is ethylbenzene with two hydrogen atoms taken off, the 'S' in ABS. Kearby's process (US 2,395,875, 1946) passes the hydrocarbon with plenty of steam over a catalyst of magnesia with iron oxide and a little potassium and copper oxide at 1100–1300 °F (about 590–700 °C). The steam dilutes the vapour and burns off coke, and the catalyst is regenerated every few hours. The patent's worked figures are for butene; for ethylbenzene it gives these general conditions, which we use.
The picture: our diagram.
Juu
Continuous
Maagizo
1
1
Make the catalyst
Make the catalyst
Mix magnesia with ferric nitrate solution, adding ammonia to precipitate all the iron as hydroxide. Wash, then mix in copper nitrate and potassium nitrate solutions. Dry, heat to 1000 °F (about 540 °C) and press into pills. Aim for about 72.4 % MgO, 18.4 % Fe2O3, 4.6 % K2O and 4.6 % CuO (amounts as required).
Zana zinazohitajika:
Oksidi ya magnesiamu
Nitrati ya feri
Myeyusho wa amonia - asilimia 25-28
Nitrati ya shaba
Nitrati ya potasiamu (chumvi ya baruti)
Maji yaliyosafishwa kwa mvuke
Kifaneli cha Büchner (kauri)
Karatasi ya Kuchuja
Tanuri la kukaushia
Tanuri ya muffle
Mashine ya kubana vidonge
Mizani ya mizani-mbili
Miwani ya kinga dhidi ya kemikali
Glavu za mpira2
2
Pass ethylbenzene and steam over it
Pass ethylbenzene and steam over it
Fill a tube reactor with the pills and hold it at 1100–1300 °F (about 590–700 °C). Feed ethylbenzene vapour with 4 to 8 volumes of steam per volume, at 100–1000 volumes of hydrocarbon per volume of catalyst an hour.
Vifaa kwa hatua hii:
Ethilibenzini1 kipandeZana zinazohitajika:
Riakta ya mirija yenye kitanda kisichohamishika
Boila ya mvuke
Pampu ya kuhamishia
Themokapo yenye kionyeshi3
3
Regenerate every few hours
Regenerate every few hours
After ½ to 7 hours, shut off the hydrocarbon and pass steam, air or both through the catalyst at 1100–1300 °F to burn off the coke, then resume.
Zana zinazohitajika:
Boila ya mvuke
Riakta ya mirija yenye kitanda kisichohamishika
Themokapo yenye kionyeshi4
4
Condense and distil
Condense and distil
Ours: condense the product, run off the water layer, and distil the styrene from the unchanged ethylbenzene, which goes back to the reactor (the patent recycles it).
Zana zinazohitajika:
Koili ya kifidishaji
Faneli ya kutenganisha
Nguzo ya kunereka kwa ombweVifaa
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