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High-Pressure Polyethylene
Karen

작성자

Karen

22. 9월 2026SE
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High-Pressure Polyethylene

In March 1933 Eric Fawcett and Reginald Gibson at ICI squeezed ethylene gas with benzaldehyde to about 1400 atmospheres and found a white waxy solid in the vessel. It could not be repeated reliably until 1935, when Michael Perrin's team traced the trick to a trace of oxygen that started the chains. The product was polyethylene - light, tough, a superb electrical insulator, and soon the cable insulation of wartime radar. **US 2,153,553**, "Polymerization of olefins", Fawcett, Gibson and Perrin, assigned to Imperial Chemical Industries, granted 11. April 1939, claims "subjecting ethylene to a pressure above about 500 atmospheres and a temperature above about 100 C"; its example runs at 2000 atmospheres and 170 °C. **Nobody reproduces 2000 atmospheres at home.** You work the polymer instead: fuse polyethylene bags into a tough sheet with an iron, then measure its density to tell high-pressure (branched, low-density) polyethylene from its later straight-chain sibling.
초급
90 minutes

안내

1

Sort the bags

Collect clean, dry carrier or produce bags marked LDPE (recycling code 4). Cut off handles and seams; open each into a flat sheet.

이 단계의 재료:

비닐봉지비닐봉지8

필요한 도구:

가위가위
2

Stack between parchment

Stack 6 layers of bag film, printed side inward, between two sheets of baking parchment. The film must never touch the iron.

이 단계의 재료:

베이킹 유산지베이킹 유산지2
3

Fuse with the iron

Iron on a low-medium setting, no steam, moving constantly for 15 seconds. Ventilate. Too hot and it shrivels and smokes - lower the setting.

필요한 도구:

스팀다리미스팀다리미
N95 방진 마스크N95 방진 마스크
4

Flip, repeat, cool

Flip and iron the other side. Peel the parchment once cool. Re-iron any bubbled patches. The layers are now one welded sheet.

필요한 도구:

스팀다리미스팀다리미
5

Pull-test both

Cut 20 mm strips from the fused sheet and from a single bag layer. Clamp each in the vise and pull with the spring scale. Record the peak force.

필요한 도구:

힘 측정기(스프링 저울)힘 측정기(스프링 저울)
바이스(만력)바이스(만력)
가위가위
6

Float test

Pour 50 ml isopropyl alcohol into a beaker. Drop in a small chip of the sheet - it sinks. Add water 10 ml at a time, stirring, then 1 ml at a time once the chip starts to lift, until it hangs mid-liquid. Note the total water added.

이 단계의 재료:

이소프로필 알코올 99 %이소프로필 알코올 99 %50 ml

필요한 도구:

유리 비커유리 비커
눈금 실린더눈금 실린더
피펫·스포이트 세트피펫·스포이트 세트
젓개젓개
7

Pressure, density, siblings

Jupyter 노트북 불러오는 중…
8

History & Context

**What the patent specifies:** ethylene above about 500 atm and 100 °C (preferred 1000+ atm, 150–250 °C). **Modern build (derived):** post-consumer LDPE film, fused well below its decomposition temperature. Low-pressure routes in the 1950s gave straight-chain, denser HDPE; both are still made in huge volumes because the branches that make LDPE weaker also make it softer and clearer. Limits: it creeps under load, softens around 100 °C, and burns.

재료

3

필요 도구

9

관련 블루프린트

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