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Chemical-Resistant Gloves: Butyl Latex over Natural Rubber on a Cotton Liner (Hart & Collyer, US 4,190,685, 1980)
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3. November 2026FO
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Chemical-Resistant Gloves: Butyl Latex over Natural Rubber on a Cotton Liner (Hart & Collyer, US 4,190,685, 1980)

Dipped rubber gloves built in layers on a knitted cotton liner: one coat of natural rubber, then five coats of butyl rubber, which lets very little liquid or vapour through. Each coat is dipped from latex on a porcelain hand form, and the whole glove is cured under steam and air pressure. Made in Canada to protect soldiers against chemical warfare agents; worn gloves showed no penetration in 24 hours of field use. Result: flexible, soft chemical-resistant gloves with a comfortable cotton lining. Source: J. A. Hart and J. C. Collyer, US 4,190,685 (1980), latex method. Unknown: sizes, the pigments. Picture: the patent drawing.
Lanjutan
Unknown

Arahan

1

Sew the cotton liner

Cut knitted or interlock cotton fabric to a glove shape and sew it into a glove. It stretches both ways, soaks up sweat and makes the glove easy to put on and take off. Not given: sizes, the knit.

Bahan untuk langkah ini:

Kain kait kapasKain kait kapas1 liner

Alatan diperlukan:

GuntingGunting
Mesin jahitMesin jahit
Dimensi tidak diketahuiDimensi tidak diketahui
2

Dip in coagulant

Pull the liner onto a porcelain hand form and flame it to smooth off the surface. Dip it in a 10 % solution of acetic acid in acetone, then turn the form for about 2½ minutes at 24 °C until it is dry. The coagulant sets the latex before it can soak through the cloth.

Bahan untuk langkah ini:

Asid asetik (glasier)Asid asetik (glasier)1 10 % in acetone
AsetonAseton1 solvent

Alatan diperlukan:

Acuan sarung tanganAcuan sarung tangan
Obor PropanaObor Propana
3

Dip the natural rubber coat

Dip the liner into natural rubber latex (the patent uses LOTOL 1185) and leave it 5 seconds. Draw it out, turn it upside down and let it dry. Scrub the rubber film with an abrasive cleaner, a brush and water, and dry it again.

Bahan untuk langkah ini:

Lateks getah asliLateks getah asli1 bath
Pencuci pelelasPencuci pelelas1 as needed

Alatan diperlukan:

Acuan sarung tanganAcuan sarung tangan
Berus penyentalBerus penyental
4

Mix the butyl latex bath

Mix, in parts by dry weight: butyl rubber latex 100, sulphur 3, zinc dibutyldithiocarbamate 4, zinc oxide 5, formaldehyde 0.1 as a preservative, a liquid dithiocarbamate curing accelerator 4 (Merac 255 in the patent), and 6.5 of pigments (olive drab in the patent). Not given: the pigments.

Bahan untuk langkah ini:

Lateks getah butilLateks getah butil100 parts dry
SulfurSulfur3 parts
Zink dibutilditiokarbamatZink dibutilditiokarbamat4 parts
Serbuk Zink OksidaSerbuk Zink Oksida5 parts
Larutan formaldehid (formalin 37 %)Larutan formaldehid (formalin 37 %)0.1 parts formaldehyde
Pemecut ditiokarbamat cecairPemecut ditiokarbamat cecair4 parts
Bahan tidak diketahuiBahan tidak diketahui6.5 parts pigment

Alatan diperlukan:

PengacauPengacau
5

Dip five butyl coats

Dip the glove into the butyl latex and draw it out at 10 cm per minute. At once turn the form at about 8 rpm at 24 °C until the film has gelled, then dry it upside down in an oven at 66 °C for 1 hour. Wash, dip and dry again until there are five butyl coats; do not use the abrasive cleaner on the butyl film.

Alatan diperlukan:

Acuan sarung tanganAcuan sarung tangan
Ketuhar pengeringanKetuhar pengeringan
6

Cure and finish

Dry the glove at 66 °C for 1 hour. Cure it for 3 hours in a pressure vessel with 30 psi steam in the jacket (131 °C) and 26 psi air in the chamber. Strip the gloves from the forms while hot; when cool, trim them and wash them in soapy water.

Bahan untuk langkah ini:

SabunSabun1 as needed

Alatan diperlukan:

Autoklaf mejaAutoklaf meja
GuntingGunting

Bahan

13

Alatan Diperlukan

9

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