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Venetian Borax: Refining Tincal with Lime
Charlie

Dicipta oleh

Charlie

13. Oktober 2026DE
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Venetian Borax: Refining Tincal with Lime

Native borax, tincal, came to Europe from the dried lake shores of Tibet and India coated in an earthy, soapy fat. Venice, then the Dutch, refined it in secret: the refined salt was called Venetian borax. One of their methods is recorded by Knapp, as Muspratt gives it in 1860: soften the tincal with water and a little slaked lime, wash it clean, dissolve it hot with a little chloride of calcium to take out the last of the soap, then crystallise it in lead-lined wooden cones. Borax is the flux of brazing and soldering.
Pertengahan
Several days

Arahan

1

Weigh the tincal and the additions

Weigh the tincal, about 1 per cent of its weight of slaked lime, and about 2 per cent of chloride of calcium (step 7 works it out for 10 kg).

Bahan untuk langkah ini:

Tinkal (boraks mentah)Tinkal (boraks mentah)10 kg
Kapur Mati (Kalsium Hidroksida)Kapur Mati (Kalsium Hidroksida)100 g
Kalsium kloridaKalsium klorida200 g

Alatan diperlukan:

Neraca dua piringNeraca dua piring
2

Soften it with water and lime

Soften the tincal in a small quantity of cold water in a wooden tub, and stir it about while adding the slaked lime little by little.

Bahan untuk langkah ini:

AirAir1 as required

Alatan diperlukan:

Besen kayuBesen kayu
Pendayung kayuPendayung kayu
Gogal Percikan KimiaGogal Percikan Kimia
Sarung tangan getahSarung tangan getah
3

Wash it several times

Pour off the turbid lime-water. Let the impurities settle out of it, then pour the clear liquid back over the crystals. Repeat this several times; it takes away the greater part of the soapy crust.

Alatan diperlukan:

Besen kayuBesen kayu
Pendayung kayuPendayung kayu
4

Dissolve hot with chloride of calcium

Dissolve the washed crystals in hot water and add the chloride of calcium. It turns what soap remains into an insoluble lime soap (and common salt); strain that off.

Bahan untuk langkah ini:

AirAir1 as required
ArangArang1 as required

Alatan diperlukan:

Kuali penyejatanKuali penyejatan
Relau ArangRelau Arang
PenapisPenapis
Pendayung kayuPendayung kayu
Gogal Percikan KimiaGogal Percikan Kimia
Sarung tangan getahSarung tangan getah
5

Boil down to 21 degrees Baumé

Evaporate the clear liquid to 21 degrees Baumé, a specific gravity of 1.17, checking with a hydrometer.

Bahan untuk langkah ini:

ArangArang1 as required

Alatan diperlukan:

Kuali penyejatanKuali penyejatan
Relau ArangRelau Arang
HidrometerHidrometer
6

Crystallise in lead-lined cones

Run the liquor into wooden vessels lined with lead and shaped as short inverted cones, and let it crystallise. Any deposit collects in the narrow lower part and does not spoil the crystals. Knapp adds that a little tincal stirred in before this last crystallisation keeps the crystals from splitting and flying off the work when heated for soldering.

Alatan diperlukan:

Tangki penghabluranTangki penghabluran
Kepingan plumbumKepingan plumbum
7

Knapp's additions, per 10 kg

Memuatkan buku nota Jupyter…
8

Powder it for flux

Take out the crystals, dry them and grind them in a mortar to a powder for use as flux. Keep it covered: in dry air borax slowly loses water and turns opaque on the surface.

Alatan diperlukan:

Lesung dan AluLesung dan Alu
9

Troubleshooting

Borax refining troubleshooting.

Flow

Loading...
10

History and honest limits

Muspratt (1860) gives Knapp's two known methods of the secret Venetian and Dutch refining; this is the lime method. The other washed the powdered tincal with caustic soda lye and added carbonate of soda. By Muspratt's time most borax was made instead from the boracic acid of Tuscany and carbonate of soda. Knapp's per cent figures do not say of what; we take them as per cent of the tincal. Grinding the crystals to powder is ours.

Bahan

5

Alatan Diperlukan

12

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