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Polypropylene Pellets by Bulk Polymerisation in Liquid Propylene
Charlie

Ṣẹ́dá nipasẹ̀

Charlie

17. Oṣù Kẹwà 2026DE
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Polypropylene Pellets by Bulk Polymerisation in Liquid Propylene

Polypropylene is propylene strung into long chains. In the bulk process the propylene itself is the liquid: kept liquid at 30–40 atm, it polymerises at 60–80 °C on a catalyst of titanium tetrachloride on magnesium chloride. Letting the pressure down boils off the unreacted propylene and leaves a powder, which is extruded into pellets. Natta found the regular (isotactic) form in 1954. The picture: our diagram of reactor, flash and pelletiser.
Ilọsíwájú
Continuous

Ìlànà

1

Polymerise in liquid propylene

Feed propylene and the TiCl4-on-MgCl2 catalyst into the reactor. Hold it at 30–40 atm so the propylene stays liquid, at 60–80 °C.

Àwọn ohun èlò fún ìgbésẹ̀ yìí:

PropylenePropylene1 t

Àwọn irinṣẹ́ tí a nílò:

Ìkòkò ìṣesí ìfúnpáÌkòkò ìṣesí ìfúnpá
Èròjà ìyára Ziegler-Natta (TiCl4 lórí MgCl2)Èròjà ìyára Ziegler-Natta (TiCl4 lórí MgCl2)
Ẹ̀rọ ìfun gáàsìẸ̀rọ ìfun gáàsì
2

Let the pressure down

Release the pressure: the unreacted propylene boils off and the polymer is left as a fine powder. Compress the propylene and return it.

Àwọn irinṣẹ́ tí a nílò:

Ẹ̀rọ ìfun gáàsìẸ̀rọ ìfun gáàsì
3

Pelletise

Melt the powder in the extruder, with any additives the grade needs, and cut the strand into pellets.

Àwọn irinṣẹ́ tí a nílò:

Ẹ̀rọ ìtújáde ṣíṣuẸ̀rọ ìtújáde ṣíṣu
4

Pressure units

Ń ṣí ìwé Jupyter…

Àwọn ohun-èlò

1

Àwọn irinṣẹ́ tó nílò

4

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