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Titanium: Titanium Tetrachloride Heated with Sodium in a Steel Bomb (Hunter, Thorpe 1913)
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Titanium: Titanium Tetrachloride Heated with Sodium in a Steel Bomb (Hunter, Thorpe 1913)

Sodium strips the chlorine from titanium tetrachloride inside a sealed steel bomb, leaving titanium metal in common salt. Result: very pure titanium that looks like polished steel; hard and brittle cold, forgeable at low red heat, melting at 1800–1850 °C. Source: Thorpe, Dictionary of Applied Chemistry vol. 5 (1913), p. 501, after Hunter (J. Amer. Chem. Soc. 1910, 32, 330). Thorpe does not say how the titanium is freed from the salt; ours follows Nagesh, Titanium Extraction Metallurgy (IntechOpen, 2023). Picture drawn by Youblob.
Ilọsíwájú
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Ìlànà

1

Charge the steel bomb

Weigh pure titanium tetrachloride and about half its weight of sodium into a steel bomb, and close it.

Àwọn ohun èlò fún ìgbésẹ̀ yìí:

Titanium tetrachlorideTitanium tetrachloride1 as required

Àwọn irinṣẹ́ tí a nílò:

Sódíọ̀mùSódíọ̀mù
Òṣùwọ̀n Díjítà PípéÒṣùwọ̀n Díjítà Pípé
Bọ́ǹbù irinBọ́ǹbù irin
2

Heat to low red heat

Heat the bomb to a low red heat. Ours: a muffle furnace.

Àwọn irinṣẹ́ tí a nílò:

Ààrò muffleÀàrò muffle
Ẹmú Ìkòkò Ìyọ́Ẹmú Ìkòkò Ìyọ́
3

Free the titanium

Ours, after Nagesh, Titanium Extraction Metallurgy (IntechOpen, 2023): leach the reaction product with water, which dissolves the sodium chloride and the leftover sodium and leaves the titanium. Leftover sodium reacts violently with water and gives off hydrogen: add the product to the water a little at a time, away from flames. Ours: dry the metal in an oven.

Àwọn irinṣẹ́ tí a nílò:

OmiOmi
Ago GílásìAgo Gílásì
Ààrò ìgbẹ̀Ààrò ìgbẹ̀

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