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Carbon Electrode: Oil-Coke Pressed with Tar and Baked at 1200° (Thorpe, 1912)
Amorphous carbon electrodes as made for aluminium reduction: oil-coke is selected, ground and calcined, pressed hard with tar as a binder, and baked at about 1200° in a kiln like a pottery kiln, packed in carbon so the surface does not burn.
A good electrode conducts electricity well but heat poorly, is hard, resists surface oxidation, has low porosity and is even throughout. Thorpe gives 25 to 60 amperes per square inch as the permissible current density, though much less is used in practice.
Not given: the tar proportion, the pressure and the sizes.
Source: T. E. Thorpe, Dictionary of Applied Chemistry vol. I (1912), p. 107. Picture: the book's text.
Advanced
Unknown
Instructions
1
1
Grind and calcine the coke
Grind and calcine the coke
Select the oil-coke carefully for low ash, volatile matter and sulphur. Grind it and calcine it. Ours: the ball mill and the kiln for calcining.
Materials for this step:
Petroleum Coke1 carefully selectedTools needed:
Iron Ball Mill
High-fire Kiln2
2
Press with tar
Press with tar
Mix the ground coke with tar as a binder and press it into blocks under high pressure. Ours: a hydraulic press.
Materials for this step:
Coal Tar1 binder
Unknown Dimensions1 pieceTools needed:
Hydraulic Press3
3
Bake in carbon
Bake in carbon
Embed the blocks in carbon, which protects their surface from oxidation, and bake them at about 1200° in a kiln built on the lines of a pottery kiln. Ours: petroleum coke as the packing.
Tools needed:
High-fire Kiln
Petroleum CokeMaterials
3- 1 carefully selectedPlaceholder
- 1 binderPlaceholder
- 1 piecePlaceholder
Tools Required
4- Placeholder
- Placeholder
- Placeholder
- Placeholder
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