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Chemical-Resistant Gloves: Butyl Latex over Natural Rubber on a Cotton Liner (Hart & Collyer, US 4,190,685, 1980)
Tex

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Tex

3. Nobyembre 2026FO
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Chemical-Resistant Gloves: Butyl Latex over Natural Rubber on a Cotton Liner (Hart & Collyer, US 4,190,685, 1980)

Dipped rubber gloves built in layers on a knitted cotton liner: one coat of natural rubber, then five coats of butyl rubber, which lets very little liquid or vapour through. Each coat is dipped from latex on a porcelain hand form, and the whole glove is cured under steam and air pressure. Made in Canada to protect soldiers against chemical warfare agents; worn gloves showed no penetration in 24 hours of field use. Result: flexible, soft chemical-resistant gloves with a comfortable cotton lining. Source: J. A. Hart and J. C. Collyer, US 4,190,685 (1980), latex method. Unknown: sizes, the pigments. Picture: the patent drawing.
Abantado
Unknown

Mga Tagubilin

1

Sew the cotton liner

Cut knitted or interlock cotton fabric to a glove shape and sew it into a glove. It stretches both ways, soaks up sweat and makes the glove easy to put on and take off. Not given: sizes, the knit.

Mga materyales para sa hakbang na ito:

Niniting na telang kotonNiniting na telang koton1 liner

Mga kailangang kasangkapan:

GuntingGunting
Makinang panahiMakinang panahi
Hindi alam na sukatHindi alam na sukat
2

Dip in coagulant

Pull the liner onto a porcelain hand form and flame it to smooth off the surface. Dip it in a 10 % solution of acetic acid in acetone, then turn the form for about 2½ minutes at 24 °C until it is dry. The coagulant sets the latex before it can soak through the cloth.

Mga materyales para sa hakbang na ito:

Acetic acid (glacial)Acetic acid (glacial)1 10 % in acetone
AcetoneAcetone1 solvent

Mga kailangang kasangkapan:

Hulmahang pang-gwantes (glove former)Hulmahang pang-gwantes (glove former)
Sulô ng PropanoSulô ng Propano
3

Dip the natural rubber coat

Dip the liner into natural rubber latex (the patent uses LOTOL 1185) and leave it 5 seconds. Draw it out, turn it upside down and let it dry. Scrub the rubber film with an abrasive cleaner, a brush and water, and dry it again.

Mga materyales para sa hakbang na ito:

Likas na latex ng gomaLikas na latex ng goma1 bath
Panlinis na may pangkiskisPanlinis na may pangkiskis1 as needed

Mga kailangang kasangkapan:

Hulmahang pang-gwantes (glove former)Hulmahang pang-gwantes (glove former)
Brotsa sa pagkuskosBrotsa sa pagkuskos
4

Mix the butyl latex bath

Mix, in parts by dry weight: butyl rubber latex 100, sulphur 3, zinc dibutyldithiocarbamate 4, zinc oxide 5, formaldehyde 0.1 as a preservative, a liquid dithiocarbamate curing accelerator 4 (Merac 255 in the patent), and 6.5 of pigments (olive drab in the patent). Not given: the pigments.

Mga materyales para sa hakbang na ito:

Butyl rubber latexButyl rubber latex100 parts dry
AsupreAsupre3 parts
Zinc dibutyldithiocarbamateZinc dibutyldithiocarbamate4 parts
Pulbos ng Zinc OxidePulbos ng Zinc Oxide5 parts
Solusyon ng formaldehyde (37 % na formalin)Solusyon ng formaldehyde (37 % na formalin)0.1 parts formaldehyde
Likidong dithiocarbamate acceleratorLikidong dithiocarbamate accelerator4 parts
Hindi kilalang materyalHindi kilalang materyal6.5 parts pigment

Mga kailangang kasangkapan:

PanghaloPanghalo
5

Dip five butyl coats

Dip the glove into the butyl latex and draw it out at 10 cm per minute. At once turn the form at about 8 rpm at 24 °C until the film has gelled, then dry it upside down in an oven at 66 °C for 1 hour. Wash, dip and dry again until there are five butyl coats; do not use the abrasive cleaner on the butyl film.

Mga kailangang kasangkapan:

Hulmahang pang-gwantes (glove former)Hulmahang pang-gwantes (glove former)
Hurnong pantuyoHurnong pantuyo
6

Cure and finish

Dry the glove at 66 °C for 1 hour. Cure it for 3 hours in a pressure vessel with 30 psi steam in the jacket (131 °C) and 26 psi air in the chamber. Strip the gloves from the forms while hot; when cool, trim them and wash them in soapy water.

Mga materyales para sa hakbang na ito:

SabonSabon1 as needed

Mga kailangang kasangkapan:

Autoclave na pang-mesaAutoclave na pang-mesa
GuntingGunting

Mga Materyales

13

Mga Kinakailangang Kasangkapan

9

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