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Tannic Acid: Chinese Galls Extracted with Warm Water, Shaken with Ether and Dried on Tin Sheets
This is the large-scale way to make commercial tannin, as Thorpe's Dictionary (1913) gives it. Chinese galls from sumach hold as much as 70 % tannin; the best oak galls, from Aleppo, 50–60 %. The powder is extracted with warm water, and the extract is shaken with ether. After several days the ether layer on top is taken off; the tannin stays in the lower layer, which is dried on hot tin sheets until it puffs up. The product still holds some gallic acid, wax and glucose. Ether is very flammable: no flame.
The picture: our diagram.
Katamtaman
1 week
Mga Tagubilin
1
1
Extract the powdered galls with warm water
Extract the powdered galls with warm water
Powder Chinese galls finely. Stir with enough water at 50–60 °C to make a strong extract. Filter it clear.
Mga materyales para sa hakbang na ito:
Mga Gall na Tsino1 as requiredMga kailangang kasangkapan:
Tubig
Batong Almires at Panghalo
Panghalo
Water Bath
Termometrong Panlaboratoryo
Papel na Pansala
Embudong Salamin na May Tangkay2
2
Shake with a quarter volume of ether
Shake with a quarter volume of ether
Add ether, one quarter of the extract's volume, and agitate until it forms an emulsion. Let it stand for several days.
Mga kailangang kasangkapan:
Diethyl ether
Embudong panghiwalay
Kabinet ng usok (may tubo)
Salamin Laban sa Tilamsik ng Kemikal
Gwantes na goma3
3
Take off the ether layer and recover the ether
Take off the ether layer and recover the ether
Remove the upper ether layer. Run the lower layer, which holds all the tannin, into a still and distil off the ether in it to recover it. No flame near the ether.
Mga kailangang kasangkapan:
Embudong panghiwalay
Alembikong tanso
Kabinet ng usok (may tubo)4
4
Dry on tin sheets over a steam coil
Dry on tin sheets over a steam coil
Let the syrupy liquid cool, spread it on tin sheets and heat them with a steam coil. The tannin quickly puffs up and dries.
Mga kailangang kasangkapan:
Plantsa ng lata
Steam Coil
Boiler ng singaw
Gwantes na gomaMga Materyales
1- 1 as requiredPlaceholder
Mga Kinakailangang Kasangkapan
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