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Acetone by Dry Distillation of Acetate of Lime
Charlie

Yaremwe na

Charlie

11. Ukwakira 2026DE
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Acetone by Dry Distillation of Acetate of Lime

Before the cumene process, acetone was made from "acetate of lime", calcium acetate. Limestone (calcium carbonate) soaked in vinegar gives calcium acetate; when the dry salt is heated it breaks down into calcium carbonate and acetone: Ca(CH₃COO)₂ → CaCO₃ + (CH₃)₂CO. Charles Friedel reported this dry distillation in 1858, and until World War I it was the main commercial way to make acetone. The calcium carbonate is left behind in the retort and the acetone distils over.
Hagati
2–3 days

Amabwiriza

1

Make calcium acetate

Soak crushed limestone in vinegar. The acetic acid dissolves the calcium carbonate as calcium acetate.

Ibikoresho by'iyi ntambwe:

Karubonate ya Kalisiyumu - Ibuye Ry'Isarabwayi RimenaguritseKarubonate ya Kalisiyumu - Ibuye Ry'Isarabwayi Rimenaguritse1 as required
InkarabyoInkarabyo1 as required

Ibikoresho bikenewe:

Ikigega cyo kugwishaIkigega cyo kugwisha
2

Dry the salt

Draw off the solution and evaporate the water to leave dry calcium acetate.

Ibikoresho bikenewe:

Igikoresho cyuka amaziIgikoresho cyuka amazi
3

Dry-distil

Heat the dry calcium acetate in a closed retort. It decomposes into calcium carbonate, which stays behind, and acetone, which comes off as vapour; condense it.

Ibikoresho bikenewe:

Icyuma cyo kubiraIcyuma cyo kubira
Umuzingo w'ikondanseriUmuzingo w'ikondanseri

Ibikoresho

2

Ibikoresho bikenewe

4

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