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Barium: Barium Oxide Heated with Aluminium at 1200 °C in Vacuum (Guntz, Thorpe 1912)
Aluminium pulls the oxygen from barium oxide at 1200 °C. In a vacuum the freed barium boils off and condenses as metal in the cool end of the tube.
Result: silver-white barium, up to 98.8 % pure. It burns easily in air; Thorpe keeps barium in dry carbon dioxide.
Source: Thorpe, Dictionary of Applied Chemistry vol. 1 (1912), p. 418, after Guntz. Not given: the tube, amounts and time. Picture drawn by Youblob.
Hejuru
1 day
Amabwiriza
1
1
Mix oxide with one-tenth aluminium
Mix oxide with one-tenth aluminium
Weigh barium oxide and mix it with one-tenth of its weight of aluminium. Ours: aluminium powder.
Ibikoresho by'iyi ntambwe:
Okiside ya bariyumu1 as requiredIbikoresho bikenewe:
Ifu ya Aluminiyumu
Iminzani ya Digitale Nyayo
Isekuru n'Umuhini by'Ibuye2
2
Heat to 1200 °C in vacuum
Heat to 1200 °C in vacuum
Heat the mixture to 1200 °C in an evacuated tube. Ours: a porcelain tube in a tube furnace on a vacuum pump. Barium vapour attacks glass; in his other method Guntz lines the tube with nickel foil.
Ibikoresho bikenewe:
Umuyoboro wa Porcelaine
Itanura ry'umuyoboro
Pirometero
Pompe ikuramo umwuka3
3
Collect the metal from the cool end
Collect the metal from the cool end
The barium condenses in the cooler part of the tube. Take it out and keep it in dry carbon dioxide; it oxidises fast in air.
Ibikoresho bikenewe:
Umuyoboro wa PorcelaineIbikoresho
1- 1 as requiredUmwanya
Ibikoresho bikenewe
7- Umwanya
- Umwanya
- Umwanya
- Umwanya
- Umwanya
- Umwanya
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