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Chromium Metal: Chromic Oxide Reduced by Aluminium (Thermit)
Aluminium takes the oxygen from chromic oxide with so much heat that the chromium comes out molten. Thorpe (1912-13) gives Goldschmidt's thermit: chromic oxide mixed with aluminium powder in a magnesia-lined crucible, lit through a fuse of aluminium powder and barium peroxide with a magnesium ribbon. The heat carries the reaction through the whole charge, and carbon-free chromium sinks under a slag of alumina. White heat: outdoors on dry sand, face shield, stand well back.
The picture: chromium metal (Wikimedia Commons).
Hejuru
1 day
Amabwiriza
1
1
Line the crucible
Line the crucible
Line a refractory crucible with a paste of magnesia and water glass, and let it dry fully.
Ibikoresho bikenewe:
Ikirahure cy'Ibumba Rirwanya Umuriro
Okiside ya magnesiyumu
Ikirahure cy'amazi (umuti wa silikate ya sodiyumu)2
2
Mix the charge
Mix the charge
Weigh 150 g of dry chromic oxide and 50 g of aluminium powder, a little less than the 53 g the equation needs, and mix them intimately.
Ibikoresho by'iyi ntambwe:
Okiside ya Kromu150 g
Ifu ya Aluminiyumu50 gIbikoresho bikenewe:
Umunzani w'ibiro
Isekuru n'Umuhini3
3
Set the fuse
Set the fuse
Stand the crucible on dry sand outdoors and fill in the charge. On top put a small heap of aluminium powder mixed with barium peroxide, and push a strip of magnesium ribbon into it.
Ibikoresho by'iyi ntambwe:
Ifu ya Aluminiyumu1 igice
Perokside ya bariyumu1 igice
Agatambaro ka Magineziyumu1 igiceIbikoresho bikenewe:
Indobo y'umucanga wumye4
4
Light it and stand back
Light it and stand back
Face shield on. Light the end of the ribbon and step well back. The fuse fires the charge and the reaction runs through it by its own heat.
Ibikoresho bikenewe:
Iterankuba
Ingabo y'Isura
Uturindantoki tw'Uruhu5
5
Break out the regulus
Break out the regulus
Let it cool completely. Break away the alumina slag on top and take out the button of chromium from the bottom. At most 103 g can form from 150 g of oxide.
Ibikoresho bikenewe:
Inyundo
Uturindantoki tw'Uruhu
Ingabo y'Isura
Icupa ry'Ikirahure Rifite UmufunikoIbikoresho
4- 150 gUmwanya
- 1 igiceUmwanya
- 1 igiceUmwanya
- 1 igiceUmwanya
Ibikoresho bikenewe
11- Umwanya
- Umwanya
- Umwanya
- Umwanya
- Umwanya
- Umwanya
- Umwanya
- Umwanya
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