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Fired Silver Paint: Precipitated Silver and Flux in Polyvinyl Alcohol with Ammonia (Gray, Erie Resistor 1954, Ex. 1)
Ed

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Ed

28. Ukwakira 2026FI
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Fired Silver Paint: Precipitated Silver and Flux in Polyvinyl Alcohol with Ammonia (Gray, Erie Resistor 1954, Ex. 1)

A paint for putting silver electrodes on ceramic, glass or mica. Fine silver powder and a little ceramic flux are held in polyvinyl alcohol dissolved in water, with a trace of ammonia to make the wet paint conduct. So a capacitor can be measured while it is being painted. On firing, the silver becomes a film held on by the flux. The silver settles, so stir while painting. Source: Robert B. Gray, US 2,695,275 (Erie Resistor, 1954), Example 1. Not given: how the silver was precipitated, which flux, the form of the ammonia, and the firing heat. Ours: precipitated silver made by reducing silver chloride with zinc, bismuth subnitrate as the flux (one Gray names), and strong ammonia water. Picture drawn by Youblob.
Utangiye
1 day

Amabwiriza

1

Dissolve 4 g polyvinyl alcohol in the water

For 100 g of paint: dissolve 4 g polyvinyl alcohol in the water, warming it to help it dissolve. The water is the balance, about 35 to 44 g. Warming is ours.

Ibikoresho by'iyi ntambwe:

Ifu ya polyvinyl alcoholIfu ya polyvinyl alcohol4 g
Amazi YatunganyijweAmazi Yatunganyijwe1 as required

Ibikoresho bikenewe:

Umunzani w'ibiroUmunzani w'ibiro
Igikombe cya BorosilikateIgikombe cya Borosilikate
Urubaho rushyushyaUrubaho rushyushya
Agati k'ikirahure cya borosilikateAgati k'ikirahure cya borosilikate
2

Grind in 50 g precipitated silver and the flux

Grind 50 g precipitated silver and 2 to 10 g ceramic flux into the solution until smooth. Gray allows some silver chloride left in the silver. Ours: silver from the zinc route, and bismuth subnitrate, one of the fluxes Gray names. The right amount of flux depends on the ceramic.

Ibikoresho by'iyi ntambwe:

Feza yaguye hasiFeza yaguye hasi50 g
Sub-nitrate ya bismuthSub-nitrate ya bismuth1 as required

Ibikoresho bikenewe:

Umunzani w'ibiroUmunzani w'ibiro
Isekuru n'UmuhiniIsekuru n'Umuhini
Uturindantoki twa NitirileUturindantoki twa Nitirile
3

Add 0.2 to 1 % ammonia

Stir in ammonia, 0.2 to 1 % of the paint. It evaporates from the film but makes the wet paint conduct. Ours: added as strong ammonia water. Sharp fumes: work in air, goggles.

Ibikoresho by'iyi ntambwe:

Umuti wa amoniyake wa 25-28 %Umuti wa amoniyake wa 25-28 %1 as required

Ibikoresho bikenewe:

Agati k'ikirahure cya borosilikateAgati k'ikirahure cya borosilikate
Amadarubindi yo Kwirinda IbinyabutabireAmadarubindi yo Kwirinda Ibinyabutabire
Uturindantoki twa NitirileUturindantoki twa Nitirile
4

Stir while painting

The silver in this paint settles, so stir it while it is being applied.

Ibikoresho bikenewe:

Agati k'ikirahure cya borosilikateAgati k'ikirahure cya borosilikate

Ibikoresho

5

Ibikoresho bikenewe

7

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