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Fructose: Invert Sugar Separated with Lime as Calcium Laevulosate
Fructose (laevulose) is the fruit sugar; ordinary sugar is fructose and glucose joined. Thorpe's Dictionary (1912) separates them: invert the sugar with acid, then stir lime into the ice-cold solution. The fructose comes down as calcium laevulosate, which hardly dissolves in ice water, while the glucose stays in solution. Carbon dioxide then frees the fructose. It melts at 95 °C and is sweeter than ordinary sugar.
The picture: our diagram.
Hagati
1–2 days
Amabwiriza
1
1
Invert the sugar
Invert the sugar
Warm a sugar solution with a little mineral acid to split it into glucose and fructose (invert sugar). Ours: dilute sulphuric acid, as required.
Ibikoresho by'iyi ntambwe:
Isukari y'umweru1 igiceIbikoresho bikenewe:
Aside ya sulifuriki yoroheje
Amazi Yatunganyijwe
Isafuriya nini y'icyuma kitagira ingese
Urubaho rushyushya
Amadarubindi yo Kwirinda Ibinyabutabire
Uturindantoki tw'ikawusu2
2
Remove the acid with baryta
Remove the acid with baryta
Neutralise the acid with baryta (ours: barium oxide) and filter off the barium sulphate. Make the invert sugar up to a 10 % solution.
Ibikoresho bikenewe:
Okiside ya bariyumu
Urupapuro rwerekana pH
Akayunguruzo k'Ikirahure Gafite Umugozi
Urupapuro rwo Kuyungurura
Umunzani w'ibiro3
3
Lime it ice-cold
Lime it ice-cold
Ice-cold, add 6 g finely powdered slaked lime to every 100 cc and stir, with the vessel standing in ice water, until the milky liquid turns creamy. The fructose comes down as calcium laevulosate; the glucose stays dissolved.
Ibikoresho by'iyi ntambwe:
Ishwagara yazimye6 g per 100 mlIbikoresho bikenewe:
Igikombe cy'Ikirahure Kirwanya Ubushyuhe
Urubura rwamenwe
Igipima Ubushyuhe cy'Ubushakashatsi4
4
Filter and press
Filter and press
Filter through linen and press hard to get rid of most of the liquid.
Ibikoresho bikenewe:
Umwenda wa lino
Imashini ya sikuru ikanda igitambaro5
5
Free the fructose with carbon dioxide
Free the fructose with carbon dioxide
Suspend the pressed mass in water and pass in carbon dioxide. Filter, then evaporate the solution under vacuum over sulphuric acid: anhydrous fructose remains.
Ibikoresho bikenewe:
Gaze ya dioxyde de carbone
Amazi Yatunganyijwe
Akayunguruzo k'Ikirahure Gafite Umugozi
Urupapuro rwo Kuyungurura
Pompe ikuramo umwuka
Asidi ya sulifurike ikomeyeIbikoresho
2- 1 igiceUmwanya
- 6 g per 100 mlUmwanya
Ibikoresho bikenewe
19- Umwanya
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