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Neodymium Magnets, Sample 7: 77Fe-8B-15Nd Sintered (Sagawa 1988)
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Neodymium Magnets, Sample 7: 77Fe-8B-15Nd Sintered (Sagawa 1988)

Neodymium magnets are iron, boron and neodymium. Sagawa's team at Sumitomo melted the three together, ground the casting to a powder finer than 10 µm, lined the grains up in a magnetic field while pressing them, and sintered the compact in argon. This is their sample 7, 77 % iron, 8 % boron and 15 % neodymium by atoms: 32.1 MGOe. Source: M. Sagawa et al. (Sumitomo Special Metals), US 4,770,723 (1988). Unknown: how the pure iron, the ferroboron and the neodymium metal are made; the patent does not say. The magnetising is ours, after Przybylski et al., Sensors 16:569 (2016). The 1 kg weights are our arithmetic from the patent's atomic percentages. Picture: the patent's Fig. 8.
Impuguke
2 days

Amabwiriza

1

Weigh sample 7: 77 Fe, 8 B, 15 Nd

Sample 7 is 77 % iron, 8 % boron and 15 % neodymium by atoms. Use 99.9 % electrolytic iron, ferroboron (19.38 % B, 5.32 % Al, 0.74 % Si, 0.03 % C, the rest iron) and neodymium of 99.7 % or better. Ours: a 1 kg melt, by arithmetic: 605.7 g iron, 68.1 g ferroboron, 330.3 g neodymium. Unknown: how these three are made.

Ibikoresho by'iyi ntambwe:

Icyuma cyo mu mashanyaraziIcyuma cyo mu mashanyarazi605.7 g
FerroboronFerroboron68.1 g
Icyuma cya neodymiumIcyuma cya neodymium330.3 g

Ibikoresho bikenewe:

Umunzani w'ibiroUmunzani w'ibiro
2

Melt by high frequency in argon and cast

Melt the charge in a high-frequency (induction) furnace under argon and pour it into a water-cooled copper mould.

Ibikoresho bikenewe:

Itanura rya inductionItanura rya induction
Ikirahure cy'Ibumba Rirwanya UmuriroIkirahure cy'Ibumba Rirwanya Umuriro
ArigoniArigoni
Ibariro rya gazi ifite igitutuIbariro rya gazi ifite igitutu
Ifumbiro ry’umuringa rikonjeshwa n’amaziIfumbiro ry’umuringa rikonjeshwa n’amazi
Uturindantoki twihanganira ubushyuheUturindantoki twihanganira ubushyuhe
3

Stamp to 35 mesh, ball-mill to 3-10 µm

Crush the casting in a stamp mill until it passes a 35-mesh sieve. Then grind it in a ball mill for 3 hours, to 3-10 µm.

Ibikoresho bikenewe:

Imashini Ikoma AmabuyeImashini Ikoma Amabuye
Agatsiko k'utuyungurizo (imyobo itandukanye)Agatsiko k'utuyungurizo (imyobo itandukanye)
Urusyo rw'imipira y'icyumaUrusyo rw'imipira y'icyuma
Amadarubindi y'umutekanoAmadarubindi y'umutekano
4

Press in a 10 kOe field at 1.5 t/cm²

Line the powder up in a magnetic field of 10 kOe and press it at 1.5 tonnes per cm². Unknown: the size and shape of the magnets.

Ibikoresho bikenewe:

Imashini ikanda ifite umurima wa rukuruziImashini ikanda ifite umurima wa rukuruzi
5

Sinter in argon at 1000-1200 °C

Sinter the compacts at 1000-1200 °C for about one hour in argon, then let them cool. Sample 7 measured 12.1 kG remanence, 7.3 kOe coercivity and 32.1 MGOe.

Ibikoresho bikenewe:

Itanura ry'umuyoboroItanura ry'umuyoboro
ArigoniArigoni
Ibariro rya gazi ifite igitutuIbariro rya gazi ifite igitutu
Uturindantoki twihanganira ubushyuheUturindantoki twihanganira ubushyuhe
6

Magnetise the magnets

Ours, after Przybylski et al., Sensors 16:569 (2016): put each magnet in the coil of an impulse magnetiser and discharge a capacitor bank through it. They found a field of 1200 kA/m enough to saturate N38 sintered Nd-Fe-B; their magnetiser used a 1 mF bank charged up to 5000 V, a thyristor switch and a 440-turn coil of 3 mm copper wire with an 80 mm bore.

Ibikoresho bikenewe:

Imashini itera rukuruziImashini itera rukuruzi

Ibikoresho

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Ibikoresho bikenewe

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