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Venetian Borax: Refining Tincal with Lime
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13. Ukwakira 2026DE
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Venetian Borax: Refining Tincal with Lime

Native borax, tincal, came to Europe from the dried lake shores of Tibet and India coated in an earthy, soapy fat. Venice, then the Dutch, refined it in secret: the refined salt was called Venetian borax. One of their methods is recorded by Knapp, as Muspratt gives it in 1860: soften the tincal with water and a little slaked lime, wash it clean, dissolve it hot with a little chloride of calcium to take out the last of the soap, then crystallise it in lead-lined wooden cones. Borax is the flux of brazing and soldering.
Hagati
Several days

Amabwiriza

1

Weigh the tincal and the additions

Weigh the tincal, about 1 per cent of its weight of slaked lime, and about 2 per cent of chloride of calcium (step 7 works it out for 10 kg).

Ibikoresho by'iyi ntambwe:

Tinkali (boraki itatunganyijwe)Tinkali (boraki itatunganyijwe)10 kg
Ishwagara yazimye (hidorogisidi ya kalisiyumu)Ishwagara yazimye (hidorogisidi ya kalisiyumu)100 g
Kloridi ya kalisiyumuKloridi ya kalisiyumu200 g

Ibikoresho bikenewe:

Umunzani w'ibiroUmunzani w'ibiro
2

Soften it with water and lime

Soften the tincal in a small quantity of cold water in a wooden tub, and stir it about while adding the slaked lime little by little.

Ibikoresho by'iyi ntambwe:

AmaziAmazi1 as required

Ibikoresho bikenewe:

Ikibindi cy'imbahoIkibindi cy'imbaho
Ikiyiko kinini cy'igitiIkiyiko kinini cy'igiti
Amadarubindi yo Kwirinda IbinyabutabireAmadarubindi yo Kwirinda Ibinyabutabire
Uturindantoki tw'ikawusuUturindantoki tw'ikawusu
3

Wash it several times

Pour off the turbid lime-water. Let the impurities settle out of it, then pour the clear liquid back over the crystals. Repeat this several times; it takes away the greater part of the soapy crust.

Ibikoresho bikenewe:

Ikibindi cy'imbahoIkibindi cy'imbaho
Ikiyiko kinini cy'igitiIkiyiko kinini cy'igiti
4

Dissolve hot with chloride of calcium

Dissolve the washed crystals in hot water and add the chloride of calcium. It turns what soap remains into an insoluble lime soap (and common salt); strain that off.

Ibikoresho by'iyi ntambwe:

AmaziAmazi1 as required
AmakaraAmakara1 as required

Ibikoresho bikenewe:

Isafuriya yo kumishaIsafuriya yo kumisha
Itanura ry'amakaraItanura ry'amakara
AkayunguruzoAkayunguruzo
Ikiyiko kinini cy'igitiIkiyiko kinini cy'igiti
Amadarubindi yo Kwirinda IbinyabutabireAmadarubindi yo Kwirinda Ibinyabutabire
Uturindantoki tw'ikawusuUturindantoki tw'ikawusu
5

Boil down to 21 degrees Baumé

Evaporate the clear liquid to 21 degrees Baumé, a specific gravity of 1.17, checking with a hydrometer.

Ibikoresho by'iyi ntambwe:

AmakaraAmakara1 as required

Ibikoresho bikenewe:

Isafuriya yo kumishaIsafuriya yo kumisha
Itanura ry'amakaraItanura ry'amakara
Igipima ubwuzuzanye bw'amaziIgipima ubwuzuzanye bw'amazi
6

Crystallise in lead-lined cones

Run the liquor into wooden vessels lined with lead and shaped as short inverted cones, and let it crystallise. Any deposit collects in the narrow lower part and does not spoil the crystals. Knapp adds that a little tincal stirred in before this last crystallisation keeps the crystals from splitting and flying off the work when heated for soldering.

Ibikoresho bikenewe:

Ikigega cyo gukora kirisitaliIkigega cyo gukora kirisitali
Urupapuro rw'isasuUrupapuro rw'isasu
7

Knapp's additions, per 10 kg

Gupakira ikaye ya Jupyter…
8

Powder it for flux

Take out the crystals, dry them and grind them in a mortar to a powder for use as flux. Keep it covered: in dry air borax slowly loses water and turns opaque on the surface.

Ibikoresho bikenewe:

Isekuru n'UmuhiniIsekuru n'Umuhini
9

Troubleshooting

Borax refining troubleshooting.

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10

History and honest limits

Muspratt (1860) gives Knapp's two known methods of the secret Venetian and Dutch refining; this is the lime method. The other washed the powdered tincal with caustic soda lye and added carbonate of soda. By Muspratt's time most borax was made instead from the boracic acid of Tuscany and carbonate of soda. Knapp's per cent figures do not say of what; we take them as per cent of the tincal. Grinding the crystals to powder is ours.

Ibikoresho

5

Ibikoresho bikenewe

12

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