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Neodymium Magnets, Sample 8: 75Fe-10B-15Nd Sintered (Sagawa 1988)
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Neodymium Magnets, Sample 8: 75Fe-10B-15Nd Sintered (Sagawa 1988)

Neodymium magnets are iron, boron and neodymium. Sagawa's team at Sumitomo melted the three together, ground the casting to a powder finer than 10 µm, lined the grains up in a magnetic field while pressing them, and sintered the compact in argon. This is their sample 8, 75 % iron, 10 % boron and 15 % neodymium by atoms: 31.9 MGOe. Source: M. Sagawa et al. (Sumitomo Special Metals), US 4,770,723 (1988). Unknown: how the pure iron, the ferroboron and the neodymium metal are made, and how the finished magnets are magnetised; the patent does not say. The 1 kg weights are our arithmetic from the patent's atomic percentages. Picture: the patent's Fig. 8.
Expert
2 days

Instructions

1

Weigh sample 8: 75 Fe, 10 B, 15 Nd

Sample 8 is 75 % iron, 10 % boron and 15 % neodymium by atoms. Use 99.9 % electrolytic iron, ferroboron (19.38 % B, 5.32 % Al, 0.74 % Si, 0.03 % C, the rest iron) and neodymium of 99.7 % or better. Ours: a 1 kg melt, by arithmetic: 584.0 g iron, 86.4 g ferroboron, 334.9 g neodymium. Unknown: how these three are made.

Materials for this step:

Electrolytic IronElectrolytic Iron584 g
FerroboronFerroboron86.4 g
Neodymium MetalNeodymium Metal334.9 g

Tools needed:

Balance ScaleBalance Scale
2

Melt by high frequency in argon and cast

Melt the charge in a high-frequency (induction) furnace under argon and pour it into a water-cooled copper mould.

Tools needed:

Induction FurnaceInduction Furnace
Clay Crucible - RefractoryClay Crucible - Refractory
ArgonArgon
Pressure Gas CylinderPressure Gas Cylinder
Water-Cooled Copper MouldWater-Cooled Copper Mould
Heat-Resistant GlovesHeat-Resistant Gloves
3

Stamp to 35 mesh, ball-mill to 3-10 µm

Crush the casting in a stamp mill until it passes a 35-mesh sieve. Then grind it in a ball mill for 3 hours, to 3-10 µm.

Tools needed:

Stamp MillStamp Mill
Sieve Set (Graded Mesh)Sieve Set (Graded Mesh)
Iron Ball MillIron Ball Mill
Safety GlassesSafety Glasses
4

Press in a 10 kOe field at 1.5 t/cm²

Line the powder up in a magnetic field of 10 kOe and press it at 1.5 tonnes per cm². Unknown: the size and shape of the magnets.

Tools needed:

Magnetic-Field PressMagnetic-Field Press
5

Sinter in argon at 1000-1200 °C

Sinter the compacts at 1000-1200 °C for about one hour in argon, then let them cool. Sample 8 measured 11.9 kG remanence, 8.0 kOe coercivity and 31.9 MGOe.

Tools needed:

Tube FurnaceTube Furnace
ArgonArgon
Pressure Gas CylinderPressure Gas Cylinder
Heat-Resistant GlovesHeat-Resistant Gloves
6

Magnetise the magnets

Unknown: how the sintered magnets are magnetised. Sagawa measures them on a B-H tracer but gives no magnetising field or apparatus.

Tools needed:

Unknown Magnetising MethodUnknown Magnetising Method

Materials

3

Tools Required

14

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