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Tannic Acid: Powdered Galls Extracted with Ether (Pelouze, Pharmacopoeia Form)
Tannic acid (gallotannin) is richest in oak galls: the best, Aleppo galls, hold 50–60 %. This is Pelouze's method in the form the British and United States pharmacopoeias adopted, as given in Thorpe's Dictionary (1913): powdered galls are first kept in moist air, then extracted with ether. The liquid splits into two layers; the lower one is a strong solution of tannic acid that dries to a porous mass. No amounts are given. Ether is very flammable: no flame, fume hood.
The picture: our diagram.
Intermediate
2 days
Instructions
1
1
Powder the galls and let them take up moisture
Powder the galls and let them take up moisture
Grind oak galls finely. Leave the powder for some time in a moist atmosphere before extracting. Ours: a mortar, then a covered tray with a damp cloth.
Materials for this step:
Oak Galls1 as requiredTools needed:
Stone Mortar and Pestle
Damp Cloth Tray2
2
Extract with ether
Extract with ether
Extract the powder with commercial ether. Ours: shake in a stoppered bottle in a fume hood, away from any flame.
Tools needed:
Diethyl Ether
Glass Bottles with Stoppers
Fume Hood (Ducted)
Chemical Splash Goggles
Rubber Gloves3
3
Separate the two layers
Separate the two layers
The extract separates into two layers. The upper is ether with gallic acid, wax and resins; the lower is a strong solution of tannic acid. Keep the lower layer. Ours: a separatory funnel.
Tools needed:
Separatory Funnel
Fume Hood (Ducted)4
4
Evaporate to a porous mass
Evaporate to a porous mass
Evaporate the lower layer; the tannic acid remains as a porous mass. Ours: an evaporating dish on a water bath, no open flame.
Tools needed:
Evaporating Dish
Water Bath
Fume Hood (Ducted)Tools Required
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