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Trisodium Phosphate: Phosphoric Acid, Soda, then Caustic Soda
Trisodium phosphate is the strongly alkaline sodium phosphate used to throw down cobalt violet. Thorpe (1913): soda added to phosphoric acid until alkaline gives disodium phosphate; excess caustic soda turns that into the trisodium salt, which crystallises in six-sided prisms. Caustic soda burns skin: gloves and goggles.
The picture: trisodium phosphate (Wikimedia Commons).
Beginner
1 day
Instructions
1
1
Phosphoric acid and soda
Phosphoric acid and soda
Goggles and gloves on. Dilute 100 g of 85 % phosphoric acid with water and stir in soda ash until the liquid is alkaline to litmus (about 92 g). Filter.
Materials for this step:
Phosphoric Acid (85%)100 g
Sodium Carbonate (soda ash)92 gTools needed:
Water
Borosilicate Beaker
Glass Stirring Rod
Litmus Paper
Fine Cotton Filter Cloth
Balance Scale
Chemical Splash Goggles
Rubber Gloves2
2
Add caustic soda
Add caustic soda
Dissolve about 40 g of caustic soda in a little water and add it to the disodium phosphate solution: a little more than the 35 g the equation needs.
Materials for this step:
Lye (Sodium Hydroxide)40 gTools needed:
Water
Borosilicate Beaker
Glass Stirring Rod
Rubber Gloves
Chemical Splash Goggles3
3
Crystallise
Crystallise
Concentrate and let it crystallise; the free alkali stays in the mother liquor. Drain the six-sided prisms and keep them in a closed jar.
Tools needed:
Evaporating Dish
Sand Bath
Glass Jars with LidsMaterials
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Tools Required
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