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Urea: Separated from Urine as the Oxalate, Freed with Chalk and Crystallised
Charlie

Created by

Charlie

21. October 2026DE
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Urea: Separated from Urine as the Oxalate, Freed with Chalk and Crystallised

Urine holds 1.5–2 % urea. Thorpe's Dictionary (1913) gives the usual way to get it out: the concentrated, filtered urine is treated with hot saturated oxalic acid, which throws down the sparingly soluble urea oxalate. Chalk breaks the oxalate up again; the liquid is cleared with animal charcoal and evaporated until urea crystallises on cooling, in needles or four-sided prisms. The picture: our diagram.
Intermediate
2 days

Instructions

1

Concentrate and filter the urine

Concentrate the urine and filter it. Ours: evaporate it in a dish on a water bath.

Materials for this step:

UrineUrine1 as required

Tools needed:

Evaporating DishEvaporating Dish
Water BathWater Bath
Hot PlateHot Plate
Filter PaperFilter Paper
Glass Funnel - StemmedGlass Funnel - Stemmed
Rubber GlovesRubber Gloves
2

Precipitate urea oxalate

Add a hot saturated solution of oxalic acid; the sparingly soluble urea oxalate separates. Collect it.

Tools needed:

Oxalic Acid DihydrateOxalic Acid Dihydrate
Distilled WaterDistilled Water
Glass BeakerGlass Beaker
StirrerStirrer
Filter PaperFilter Paper
Glass Funnel - StemmedGlass Funnel - Stemmed
Chemical Splash GogglesChemical Splash Goggles
3

Decompose with chalk, decolorise

Decompose the urea oxalate with powdered chalk (ours: whiting) and water, and filter. Decolorise the filtrate with animal charcoal and filter again.

Tools needed:

Calcium Carbonate - WhitingCalcium Carbonate - Whiting
Bone BlackBone Black
Distilled WaterDistilled Water
Glass BeakerGlass Beaker
StirrerStirrer
Filter PaperFilter Paper
Glass Funnel - StemmedGlass Funnel - Stemmed
4

Evaporate and crystallise

Evaporate the clear filtrate until urea crystallises out on cooling.

Tools needed:

Evaporating DishEvaporating Dish
Water BathWater Bath
Hot PlateHot Plate

Materials

1
  • 1 as required
    Placeholder

Tools Required

13

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