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Chromium Metal: Chromic Oxide Reduced by Aluminium (Thermit)
Aluminium takes the oxygen from chromic oxide with so much heat that the chromium comes out molten. Thorpe (1912-13) gives Goldschmidt's thermit: chromic oxide mixed with aluminium powder in a magnesia-lined crucible, lit through a fuse of aluminium powder and barium peroxide with a magnesium ribbon. The heat carries the reaction through the whole charge, and carbon-free chromium sinks under a slag of alumina. White heat: outdoors on dry sand, face shield, stand well back.
The picture: chromium metal (Wikimedia Commons).
Osezingeni eliphezulu
1 day
Imiyalelo
1
1
Line the crucible
Line the crucible
Line a refractory crucible with a paste of magnesia and water glass, and let it dry fully.
Amathuluzi adingekayo:
Imbiza Yobumba Emelana Nomlilo
I-oksayidi ye-magnesium
Ingilazi yamanzi (isisombululo se-sodium silicate)2
2
Mix the charge
Mix the charge
Weigh 150 g of dry chromic oxide and 50 g of aluminium powder, a little less than the 53 g the equation needs, and mix them intimately.
Izinto zokwakha zalesi sinyathelo:
I-Chromic Oxide150 g
Impuphu Ye-Aluminium50 gAmathuluzi adingekayo:
Isikali sesilinganiso
Isigqulo Nomgqulo3
3
Set the fuse
Set the fuse
Stand the crucible on dry sand outdoors and fill in the charge. On top put a small heap of aluminium powder mixed with barium peroxide, and push a strip of magnesium ribbon into it.
Izinto zokwakha zalesi sinyathelo:
Impuphu Ye-Aluminium1 ucezu
I-barium peroxide1 ucezu
Iribhoni Ye-Magnesium1 ucezuAmathuluzi adingekayo:
Ibhakede lesihlabathi esomile4
4
Light it and stand back
Light it and stand back
Face shield on. Light the end of the ribbon and step well back. The fuse fires the charge and the reaction runs through it by its own heat.
Amathuluzi adingekayo:
Isilayitha
Isivikelo Sobuso
Amagilavu Esikhumba5
5
Break out the regulus
Break out the regulus
Let it cool completely. Break away the alumina slag on top and take out the button of chromium from the bottom. At most 103 g can form from 150 g of oxide.
Amathuluzi adingekayo:
Isando
Amagilavu Esikhumba
Isivikelo Sobuso
Ijeke Lengilazi ElinesivaloIzinto
4- 150 gIsibambeli
- 1 ucezuIsibambeli
- 1 ucezuIsibambeli
- 1 ucezuIsibambeli
Amathuluzi Adingekayo
11- Isibambeli
- Isibambeli
- Isibambeli
- Isibambeli
- Isibambeli
- Isibambeli
- Isibambeli
- Isibambeli
- Isibambeli
- Isibambeli
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