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PTFE Resin Powder: Tetrafluoroethylene Polymerised under Pressure, Plunkett 1941
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20. uMfumfu 2026DE
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PTFE Resin Powder: Tetrafluoroethylene Polymerised under Pressure, Plunkett 1941

PTFE (polytetrafluoroethylene) is the chemically inert plastic. Roy Plunkett found that tetrafluoroethylene, kept under pressure at room temperature, slowly turns into a white solid (US 2,230,654, 1941). A little silver nitrate speeds it up: 7 parts of the gas with 0.1 part silver nitrate at 25 °C for 21 days gave 2.3 parts of polymer. The powder dissolves in nothing usual, does not burn on its own, and melts only at red heat. The picture: our diagram.
Osezingeni eliphezulu
3 weeks

Imiyalelo

1

Charge the cylinder

Put 0.1 part of silver nitrate in a steel pressure cylinder, close it and condense in 7 parts of tetrafluoroethylene, so it stands under its own pressure.

Izinto zokwakha zalesi sinyathelo:

I-TetrafluoroethyleneI-Tetrafluoroethylene7 parts

Amathuluzi adingekayo:

I-Silver NitrateI-Silver Nitrate
Isilinda segesi ecindezelweIsilinda segesi ecindezelwe
Isixhaphi esibandayoIsixhaphi esibandayo
Isikali sesilinganisoIsikali sesilinganiso
Izibuko Zokuchitheka KwamakhemikhaliIzibuko Zokuchitheka Kwamakhemikhali
Amagilavu erabhaAmagilavu erabha
2

Leave at 25 °C for 21 days

Keep the cylinder at 25 °C for 21 days. Warmer is faster. Without the silver nitrate, 10 days gave only about 7 %.

Amathuluzi adingekayo:

Isilinda segesi ecindezelweIsilinda segesi ecindezelwe
3

Remove the gas, take out the powder

Let out the unpolymerised tetrafluoroethylene (ours: into a cold trap to use again) and take out the solid polymer: about 2.3 parts, a third of the gas.

Amathuluzi adingekayo:

Isixhaphi esibandayoIsixhaphi esibandayo
Ikhabethe lomusi (elinepayipi)Ikhabethe lomusi (elinepayipi)
Amagilavu erabhaAmagilavu erabha

Izinto

1

Amathuluzi Adingekayo

7

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