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Metal Oxide Varistor: Zinc Oxide with 0.2 % Bismuth Oxide, Sintered Disc (Masuyama 1972)
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28. uMfumfu 2026FI
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Metal Oxide Varistor: Zinc Oxide with 0.2 % Bismuth Oxide, Sintered Disc (Masuyama 1972)

A non-linear resistor: the current through it rises far faster than the voltage across it. Masuyama, Matsuoka and Nishi made one from zinc oxide with a little bismuth oxide: pressed into a disc, sintered, lapped, and given metal electrodes. With 0.2 mole % bismuth oxide, sintered at 1000 °C and lapped to 1 mm, the disc measured a C-value of 43 at 1 mA and a nonlinearity exponent n of 4.3. Source: T. Masuyama, M. Matsuoka and T. Nishi (Matsushita), US 3,663,458 (1972), Example 1. Unknown: what the silver paint is. The patent calls the spraying and the paint well known. The spraying is ours, after US Army Corps of Engineers EM 1110-2-3401 (1999). The 10 g batch is our arithmetic. Picture: the patent's drawing.
Osezingeni eliphezulu
1 day

Imiyalelo

1

Weigh 99.8 ZnO to 0.2 Bi2O3 and wet-mill 5 hours

Mix zinc oxide and bismuth oxide 99.8 : 0.2 by moles. Ours, for 10 g: 9.887 g zinc oxide and 0.113 g bismuth oxide (our arithmetic). Mill wet for 5 hours, then dry. Unknown: the milling liquid.

Izinto zokwakha zalesi sinyathelo:

Impuphu Ye-Zinc OxideImpuphu Ye-Zinc Oxide9.887 g
I-bismuth oxideI-bismuth oxide0.113 g

Amathuluzi adingekayo:

Isikali sesilinganisoIsikali sesilinganiso
Umshini Wokugaya Ngamabhola EnsimbiUmshini Wokugaya Ngamabhola Ensimbi
Ihhavini yokomisaIhhavini yokomisa
2

Press discs 13 mm by 2.5 mm

Press the powder in a mould into discs 13 mm across and 2.5 mm thick at 340 kg/cm².

Amathuluzi adingekayo:

Umshini wokucindezela we-hydraulicUmshini wokucindezela we-hydraulic
Isikhunta sokucindezela idiskiIsikhunta sokucindezela idiski
I-Vernier CaliperI-Vernier Caliper
3

Sinter 1 hour at 1000 °C and furnace-cool

Sinter the discs in air for 1 hour at 1000 °C, then let them cool in the furnace to room temperature (about 15-30 °C). Above 1200 °C the disc loses its nonlinearity.

Amathuluzi adingekayo:

Isithando se-muffleIsithando se-muffle
4

Lap both faces to 1.0 mm

Lap both faces with 600-mesh silicon carbide until the disc is 1.0 mm thick.

Amathuluzi adingekayo:

Amagcubu e-silicon carbideAmagcubu e-silicon carbide
I-Vernier CaliperI-Vernier Caliper
5

Spray aluminium electrodes and attach leads

Spray a metallised film of aluminium on both faces. Attach a lead wire to each with conductive silver paint. Ours, after US Army Corps of Engineers EM 1110-2-3401 (1999): wire-arc spray the aluminium from two 3.2 mm wires melted by an 18-40 V DC arc and atomised by compressed air, 15-20 cm from the disc and never at less than 45°, in at least two coats at right angles of 50-75 µm each. Unknown: the paint.

Izinto zokwakha zalesi sinyathelo:

Isigaxa se-aluminiumIsigaxa se-aluminium1 as 3.2 mm spray wire
Upende wesiliva odlulisa ugesiUpende wesiliva odlulisa ugesi1 as required
Ucingo LwethusiUcingo Lwethusi2 izicucu

Amathuluzi adingekayo:

I-Vernier CaliperI-Vernier Caliper
Isibhamu sokufafaza nge-arc yocingoIsibhamu sokufafaza nge-arc yocingo
Umcindezeli womoya wezimboniUmcindezeli womoya wezimboni

Izinto

5

Amathuluzi Adingekayo

10

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