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Isotactic Polypropylene
Pixel

Criado por

Pixel

22. setembro 2026FI
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Isotactic Polypropylene

Propylene had always polymerised into a useless sticky mass. In March 1954 Giulio Natta's group at the Milan Polytechnic, using catalysts of the kind Karl Ziegler had just found for ethylene, made polypropylene in which every methyl group sits on the same side of the chain. They called it isotactic. The ordered chains crystallise, and a sticky nothing became a stiff, light, tough plastic. Natta and Ziegler shared the 1963 Nobel Prize in Chemistry. **US 3,112,300**, "Isotactic polypropylene", Natta, Pino and Mazzanti, assigned to Montecatini, filed 9. December 1957 (continuing an application of 8. June 1955), granted 26. November 1963. Its single claim is the arrangement itself: macromolecules "insoluble in boiling n-heptane" with the structure "shown in FIGURE 2 of the accompanying drawing". **You build the property that made it famous**: an Arduino servo rig that folds a polypropylene living hinge thousands of times, beside PET film.
Intermediário
3 hours plus flex runs

Instruções

1

Cut the hinges

Cut 80 x 20 mm strips from 0.5 mm polypropylene and from PET film. Measure both thicknesses. Fold each sharply across the middle once and flatten the crease with a fingernail - flexing it right away is how moulded hinges are made too.

Materiais para este passo:

Placa de polipropileno (A4)Placa de polipropileno (A4)1 folha
Folha de estêncil de mylarFolha de estêncil de mylar1 folha

Ferramentas necessárias:

X-ato de oficinaX-ato de oficina
RéguaRégua
Paquímetro digital de 6 polegadasPaquímetro digital de 6 polegadas
2

Build the fixture

Screw two 100 x 50 mm pine blocks side by side. Hot-glue the servo to one so its shaft sits exactly on the crease line. Clamp one leaf of the hinge to the other block with a binder clip; hot-glue the free leaf to the servo horn.

Materiais para este passo:

Tábua de pinhoTábua de pinho1 peça
Parafusos para madeiraParafusos para madeira2 peças
Micromotor servo SG90 (5 unidades)Micromotor servo SG90 (5 unidades)1 pacote

Ferramentas necessárias:

Pistola de cola quentePistola de cola quente
Molas de papel grandesMolas de papel grandes
Conjunto de chaves de fendasConjunto de chaves de fendas
3

Wire and flash the counter

Servo signal to D9, power to 5V and GND; microswitch between D2 and GND. One SG90 can run from the Uno's 5 V pin - if the board resets under load, power the servo separately with a shared GND. Open the serial monitor at 115200.
living_hinge_flex_counter.inocpp
// Living-hinge flex counter - batch 97, US 3,112,300
// Flexes a hinge 0 -> 90 degrees and back, and stops every BLOCK cycles for you to inspect it.
// Servo signal -> D9, servo + -> 5V, servo - -> GND. Microswitch between D2 and GND.
#include <Servo.h>

Servo flexer;
const int SERVO_PIN  = 9;
const int BUTTON_PIN = 2;             // microswitch to GND, internal pull-up
const int OPEN_DEG   = 0;
const int CLOSED_DEG = 90;
const unsigned long MOVE_MS = 350;    // an SG90 needs roughly 0.3 s for 90 degrees
const unsigned long BLOCK   = 1000;   // cycles between inspections; make it smaller near failure
unsigned long cycles = 0;

void waitForButton() {
  while (digitalRead(BUTTON_PIN) == HIGH) {}
  delay(50);                          // debounce
  while (digitalRead(BUTTON_PIN) == LOW) {}
}

void setup() {
  Serial.begin(115200);
  pinMode(BUTTON_PIN, INPUT_PULLUP);
  flexer.attach(SERVO_PIN);
  flexer.write(OPEN_DEG);
  Serial.println(F("Mount the hinge, then press the switch to start."));
  waitForButton();
}

void loop() {
  flexer.write(CLOSED_DEG); delay(MOVE_MS);
  flexer.write(OPEN_DEG);   delay(MOVE_MS);
  cycles++;
  if (cycles % BLOCK == 0) {
    flexer.detach();                  // rest the servo while you look
    Serial.print(cycles);
    Serial.println(F(" cycles - inspect the crease. Intact? press the switch. Cracked? note it."));
    waitForButton();
    flexer.attach(SERVO_PIN);
  }
}

Materiais para este passo:

Microinterruptor (accionado por alavanca)Microinterruptor (accionado por alavanca)1 peça
Conjunto de cabos Dupont (macho-fêmea)Conjunto de cabos Dupont (macho-fêmea)1 conjunto

Ferramentas necessárias:

Arduino Uno R3Arduino Uno R3
Breadboard - ClassicBreadboard - Classic
SparkFun Cerberus USB Cable - 1.8 meterSparkFun Cerberus USB Cable - 1.8 meter
4

Run and inspect

Press the switch to start. Every 1000 cycles it stops: look at the crease under the loupe. Whitening is normal; a crack you can see through is failure. Record the last intact count, then run the other material.

Ferramentas necessárias:

Lupa de joalheiroLupa de joalheiro
5

Strain, counts, siblings

A carregar o notebook Jupyter…
6

History & Context

**What the patent specifies:** high-molecular polypropylene made of isotactic macromolecules, insoluble in boiling n-heptane, with the structure of its FIGURE 2 (shown here). **Modern build (derived):** commercial PP sheet, creased by hand into a hinge. Montecatini began production in 1957. Moulded PP hinges now close most flip-top caps, and PP makes crates, car bumpers, rope and food tubs. Its limits: it turns brittle in deep cold, degrades in sunlight without stabilisers, and is hard to glue or paint.
Passo 6 - Image 1

Materiais

7

Ferramentas necessárias

10

CC0 Domínio Público

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