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Premium Gasoline, Research Octane 102.7: Alkylate, Reformate, Light Cracked Gasoline and Isopentane with 2.7 cc Lead (Gulf, US 3,071,535)
Premium petrol is not made in one unit: it is blended. Gulf's 1959 recipe mixes alkylate, two cuts of reformate, light catalytically cracked gasoline and isopentane, with enough butane to set its vapour pressure and a little tetraethyl lead. Gulf counts as premium any gasoline of research octane 97 or more.
Result: research octane 102.7 and motor octane 95.2 with 2.7 cc of tetraethyl lead per gallon, at 10 lb Reid vapour pressure.
Source: Condrasky & Glazier, US 3,071,535 (Gulf, filed 1959), Table III. The light cracked gasoline comes from Gulf's own cracker (FCC Gasoline); the other components are matched by kind to our blueprints that make them. Not given: blending equipment, how the cuts are made, how the lead is dosed. Danger: tetraethyl lead is a deadly poison; leaded petrol is banned for road use almost everywhere. Picture drawn by Youblob.
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Alkylate: Isobutane Joined with Cracked-Gasoline Olefins over 98 % Sulphuric Acid at 10 °C (McAllister & Ross, Shell, US 2,344,469)
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Reformate: Straight-Run Naphtha over Platinum-Alumina-Fluorine Catalyst at 874 °F and 500 psi (Haensel, UOP, US 2,479,110)
Charlie 创作
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3
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FCC Gasoline: Gas Oil Cracked over Fluidised Silica-Alumina at 975 °F, 71.5 % Conversion (Gulf, US 3,071,535)
Charlie 创作
工业
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Isopentane: the 29-30 °C Cut of the Lightest Gasoline (Mabery & Hudson 1897)
Charlie 创作
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危险
Tetraethyl Lead: Steam-Distilled from the Reaction Mass in Water Brought to pH 7.5 with Dilute Sulphuric Acid (Bake & Parmelee, du Pont, US 2,038,703)
Charlie 创作
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Normal Butane: the 0 °C Cut of the Lightest Gasoline, Distilled Twenty Times in the Cold (Mabery & Hudson 1897)
Charlie 创作
工业
2
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