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What Goes Down the Sink, and What Absolutely Does Not
Every one of the rungs before this one ends with liquid in a beaker that is no longer wanted. Where it goes is part of the method, not an afterthought, and it is the part most often left out of a written procedure.
The default answer is NOT the sink. A domestic drain runs to a treatment works designed for sewage, and it passes through metal pipes on the way — so the question is what the pipe and the works can handle, not what will disappear from view.
Getting this right is also self-interested. A drain corroded by acid, a trap full of precipitated metal, and a bench of unlabelled waste bottles are all problems that come back to the person who made them.
初学者
2 hours
说明
1
1
Neutralise and dilute what may go down
Neutralise and dilute what may go down
Dilute acids and alkalis can go to the drain once they are neutralised to roughly pH 6 to 9 and flushed with plenty of water. Check with indicator paper rather than assuming — neutralising is easy to overshoot in either direction.
Neutralise slowly, in a large vessel, with stirring, and expect heat and gas. Adding bicarbonate to acid foams vigorously, and a beaker filled to the top delivers that foam onto the bench.
Salt solutions, dilute sugar, and the water you rinsed glassware with are all fine. The test is whether what you are pouring would be a problem in a river at the concentration it arrives at — which, after the drain and the works, is very dilute indeed, but not zero.
此步骤所需材料:
碳酸氢钠1 个
水1 升所需工具:
石蕊试纸
通用指示剂溶液
玻璃烧杯
搅拌棒2
2
What never goes down: metals, solvents, solids, oils
What never goes down: metals, solvents, solids, oils
HEAVY METAL solutions — lead, mercury, cadmium, chromium, and copper in quantity — go to a labelled waste container. Treatment works cannot remove them and they accumulate in the sludge that is spread on land.
ORGANIC SOLVENTS go to a labelled solvent waste container, never to the drain. Many are flammable, most are not treatable, and a trap full of solvent vapour under a bench is a hazard that waits.
SOLIDS go in a bin or a solid waste container, not washed down — filter them out first. And OILS and greases set in the cold part of the pipe and block it. Wipe greasy glassware with paper before it goes near a sink.
所需工具:
不干胶标签
油性记号笔
滤纸
带颈玻璃漏斗3
3
One labelled container per waste stream, filled from the top down
One labelled container per waste stream, filled from the top down
Keep separate containers for aqueous metal waste, organic solvent, and halogenated solvent. Mixing streams makes all of them harder and more expensive to deal with, and some combinations react.
Label the container with what is in it as you add — not at the end. A bottle of mixed unknown liquid is the single most awkward object a workshop can produce, because nobody can treat it without first finding out what it is.
Leave headspace, keep the cap on between additions, and stand the container in a tray. A full bottle with a loose cap on an open bench is how a small waste problem becomes a large spill.
此步骤所需材料:
不干胶标签1 个所需工具:
油性记号笔
带颈玻璃漏斗4
4
Write the disposal into the method
Write the disposal into the method
A procedure that ends at "filter and collect the product" is not finished. Add the line that says what happens to the filtrate, the rinsings and the spent reagents, with the same precision as the rest.
That line is what makes the method repeatable by somebody else. Without it, the next person guesses — and the guess is almost always the sink, because it is the nearest thing.
Record quantities as well. Knowing that a run produces 400 mL of dilute copper solution lets the next person have a container ready, rather than discovering the problem with a full beaker in each hand.
所需工具:
不干胶标签
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