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Lactic Acid: Fermented Whey, Lime, Oxalic Acid and Alcohol (Louradour, US Dispensatory 1907)
Charlie

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Charlie

28. octubre 2026DE
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Lactic Acid: Fermented Whey, Lime, Oxalic Acid and Alcohol (Louradour, US Dispensatory 1907)

Whey left warm turns sour with lactic acid. Louradour's way to get the acid out: boil the whey down, take the acid up as calcium lactate with lime, then free it again with oxalic acid, which carries the lime away as an insoluble salt. A last wash in alcohol leaves the milk sugar and salts behind. Source: The Dispensatory of the United States of America (1907), Acidum Lacticum. This is pharmacopoeial lactic acid; we use it as food-grade, as ruled. The Dispensatory gives the temperature and the order of work but no amounts or times; those are stated as not given. Vessels, filter and still are ours. Picture drawn by Youblob.
Intermedio
1 week

Instrucciones

1

Sour the whey at 21-27 °C

Keep whey between 21.1 °C (70 °F) and 26.6 °C (80 °F) until it is charged with lactic acid. Not given: how long.

Materiales para este paso:

Suero de lecheSuero de leche1 as required

Herramientas necesarias:

Recipiente de vidrioRecipiente de vidrio
Termómetro de laboratorioTermómetro de laboratorio
2

Boil down to a third, then add lime

Evaporate it to one third of its bulk, decant and filter. Saturate it with milk of lime (slaked lime stirred in water). The acid becomes calcium lactate and stays dissolved; a precipitate, mostly calcium phosphate, falls. Filter again. Not given: how much lime.

Materiales para este paso:

Hidróxido de calcio (cal apagada)Hidróxido de calcio (cal apagada)1 as required
AguaAgua1 as required

Herramientas necesarias:

Cápsula de evaporaciónCápsula de evaporación
Placa calefactoraPlaca calefactora
Papel de filtroPapel de filtro
3

Free the acid with oxalic acid

Add oxalic acid: the lime falls as calcium oxalate and the lactic acid is set free. Filter a third time. The solution still holds milk sugar and some salts. Oxalic acid is poisonous if swallowed: gloves. Not given: how much.

Materiales para este paso:

Ácido oxálico dihidratadoÁcido oxálico dihidratado1 as required

Herramientas necesarias:

Recipiente de vidrioRecipiente de vidrio
Papel de filtroPapel de filtro
Guantes de nitriloGuantes de nitrilo
4

Purify with alcohol and distil it off

Concentrate to a syrup and treat it with alcohol, which dissolves the acid and throws down the milk sugar and salts. Filter, then distil off the alcohol: pure lactic acid remains.

Herramientas necesarias:

Etanol de laboratorio, 95 %Etanol de laboratorio, 95 %
Cápsula de evaporaciónCápsula de evaporación
Papel de filtroPapel de filtro
Matraz de fondo redondoMatraz de fondo redondo
Serpentín condensadorSerpentín condensador
Placa calefactoraPlaca calefactora

Materiales

4

Herramientas requeridas

9

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