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Lactic Acid: Fermented Whey, Lime, Oxalic Acid and Alcohol (Louradour, US Dispensatory 1907)
Charlie

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Charlie

28. Oktober 2026DE
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Lactic Acid: Fermented Whey, Lime, Oxalic Acid and Alcohol (Louradour, US Dispensatory 1907)

Whey left warm turns sour with lactic acid. Louradour's way to get the acid out: boil the whey down, take the acid up as calcium lactate with lime, then free it again with oxalic acid, which carries the lime away as an insoluble salt. A last wash in alcohol leaves the milk sugar and salts behind. Source: The Dispensatory of the United States of America (1907), Acidum Lacticum. This is pharmacopoeial lactic acid; we use it as food-grade, as ruled. The Dispensatory gives the temperature and the order of work but no amounts or times; those are stated as not given. Vessels, filter and still are ours. Picture drawn by Youblob.
Menengah
1 week

Instruksi

1

Sour the whey at 21-27 °C

Keep whey between 21.1 °C (70 °F) and 26.6 °C (80 °F) until it is charged with lactic acid. Not given: how long.

Material untuk langkah ini:

Air dadihAir dadih1 as required

Alat yang dibutuhkan:

Wadah kacaWadah kaca
Termometer LaboratoriumTermometer Laboratorium
2

Boil down to a third, then add lime

Evaporate it to one third of its bulk, decant and filter. Saturate it with milk of lime (slaked lime stirred in water). The acid becomes calcium lactate and stays dissolved; a precipitate, mostly calcium phosphate, falls. Filter again. Not given: how much lime.

Material untuk langkah ini:

Kalsium hidroksida (kapur padam)Kalsium hidroksida (kapur padam)1 as required
AirAir1 as required

Alat yang dibutuhkan:

Cawan PenguapCawan Penguap
Pelat PemanasPelat Pemanas
Kertas SaringKertas Saring
3

Free the acid with oxalic acid

Add oxalic acid: the lime falls as calcium oxalate and the lactic acid is set free. Filter a third time. The solution still holds milk sugar and some salts. Oxalic acid is poisonous if swallowed: gloves. Not given: how much.

Material untuk langkah ini:

Asam oksalat dihidratAsam oksalat dihidrat1 as required

Alat yang dibutuhkan:

Wadah kacaWadah kaca
Kertas SaringKertas Saring
Sarung Tangan NitrilSarung Tangan Nitril
4

Purify with alcohol and distil it off

Concentrate to a syrup and treat it with alcohol, which dissolves the acid and throws down the milk sugar and salts. Filter, then distil off the alcohol: pure lactic acid remains.

Alat yang dibutuhkan:

Etanol mutu laboratorium, 95 %Etanol mutu laboratorium, 95 %
Cawan PenguapCawan Penguap
Kertas SaringKertas Saring
Labu alas bulatLabu alas bulat
Kumparan kondensorKumparan kondensor
Pelat PemanasPelat Pemanas

Bahan

4

Alat yang Diperlukan

9

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