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Chemical-Resistant Gloves: Butyl Latex over Natural Rubber on a Cotton Liner (Hart & Collyer, US 4,190,685, 1980)
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3. Novemba 2026FO
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Chemical-Resistant Gloves: Butyl Latex over Natural Rubber on a Cotton Liner (Hart & Collyer, US 4,190,685, 1980)

Dipped rubber gloves built in layers on a knitted cotton liner: one coat of natural rubber, then five coats of butyl rubber, which lets very little liquid or vapour through. Each coat is dipped from latex on a porcelain hand form, and the whole glove is cured under steam and air pressure. Made in Canada to protect soldiers against chemical warfare agents; worn gloves showed no penetration in 24 hours of field use. Result: flexible, soft chemical-resistant gloves with a comfortable cotton lining. Source: J. A. Hart and J. C. Collyer, US 4,190,685 (1980), latex method. Unknown: sizes, the pigments. Picture: the patent drawing.
Juu
Unknown

Maagizo

1

Sew the cotton liner

Cut knitted or interlock cotton fabric to a glove shape and sew it into a glove. It stretches both ways, soaks up sweat and makes the glove easy to put on and take off. Not given: sizes, the knit.

Vifaa kwa hatua hii:

Kitambaa cha pamba kilichofumwa kwa sindanoKitambaa cha pamba kilichofumwa kwa sindano1 liner

Zana zinazohitajika:

MkasiMkasi
CherehaniCherehani
Vipimo visivyojulikanaVipimo visivyojulikana
2

Dip in coagulant

Pull the liner onto a porcelain hand form and flame it to smooth off the surface. Dip it in a 10 % solution of acetic acid in acetone, then turn the form for about 2½ minutes at 24 °C until it is dry. The coagulant sets the latex before it can soak through the cloth.

Vifaa kwa hatua hii:

Asidi asetiki (safi kabisa)Asidi asetiki (safi kabisa)1 10 % in acetone
AsetoniAsetoni1 solvent

Zana zinazohitajika:

Kalibu ya glavuKalibu ya glavu
Tochi ya PropaniTochi ya Propani
3

Dip the natural rubber coat

Dip the liner into natural rubber latex (the patent uses LOTOL 1185) and leave it 5 seconds. Draw it out, turn it upside down and let it dry. Scrub the rubber film with an abrasive cleaner, a brush and water, and dry it again.

Vifaa kwa hatua hii:

Utomvu wa mpira asiliaUtomvu wa mpira asilia1 bath
Kisafishaji cha kukwaruzaKisafishaji cha kukwaruza1 as needed

Zana zinazohitajika:

Kalibu ya glavuKalibu ya glavu
Brashi ya kusuguaBrashi ya kusugua
4

Mix the butyl latex bath

Mix, in parts by dry weight: butyl rubber latex 100, sulphur 3, zinc dibutyldithiocarbamate 4, zinc oxide 5, formaldehyde 0.1 as a preservative, a liquid dithiocarbamate curing accelerator 4 (Merac 255 in the patent), and 6.5 of pigments (olive drab in the patent). Not given: the pigments.

Vifaa kwa hatua hii:

Utomvu wa mpira wa butiliUtomvu wa mpira wa butili100 parts dry
SalfaSalfa3 parts
Zinki dibutildithiokabamatiZinki dibutildithiokabamati4 parts
Poda ya oksidi ya zinkiPoda ya oksidi ya zinki5 parts
Myeyusho wa fomaldehidi (fomalini asilimia 37)Myeyusho wa fomaldehidi (fomalini asilimia 37)0.1 parts formaldehyde
Kiharakishi cha dithiokabamati cha majimajiKiharakishi cha dithiokabamati cha majimaji4 parts
Nyenzo isiyojulikanaNyenzo isiyojulikana6.5 parts pigment

Zana zinazohitajika:

KikorogoKikorogo
5

Dip five butyl coats

Dip the glove into the butyl latex and draw it out at 10 cm per minute. At once turn the form at about 8 rpm at 24 °C until the film has gelled, then dry it upside down in an oven at 66 °C for 1 hour. Wash, dip and dry again until there are five butyl coats; do not use the abrasive cleaner on the butyl film.

Zana zinazohitajika:

Kalibu ya glavuKalibu ya glavu
Tanuri la kukaushiaTanuri la kukaushia
6

Cure and finish

Dry the glove at 66 °C for 1 hour. Cure it for 3 hours in a pressure vessel with 30 psi steam in the jacket (131 °C) and 26 psi air in the chamber. Strip the gloves from the forms while hot; when cool, trim them and wash them in soapy water.

Vifaa kwa hatua hii:

SabuniSabuni1 as needed

Zana zinazohitajika:

Otoklavu ya mezaOtoklavu ya meza
MkasiMkasi

Vifaa

13

Zana Zinazohitajika

9

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