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PET Resin: Terephthalic Acid and Ethylene Glycol, Whinfield and Dickson
PET (polyethylene terephthalate) was invented by Whinfield and Dickson, whose patent (US 2,465,319, 1949) gives this first example: boil terephthalic acid in ethylene glycol until it dissolves, wash and dry the glycol ester, then heat it at 280 °C under nitrogen until it is a viscous polymer that melts at 254–255 °C and can be drawn into fibre. The melt is extruded and cut into chips (pellets) for moulding and spinning.
The picture: our diagram.
Juu
About 4 days
Maagizo
1
1
Boil the acid in glycol
Boil the acid in glycol
Reflux 50 g terephthalic acid with 89 g ethylene glycol for about 72 hours, until it has all dissolved. This makes glycol terephthalate.
Vifaa kwa hatua hii:
Asidi ya tereftaliki50 g
Ethilini glikoli89 gZana zinazohitajika:
Mizani ya mizani-mbili
Chupa yenye chini cha mviringo
Koili ya kifidishaji
Sahani ya Kupasha Joto2
2
Wash and dry the ester
Wash and dry the ester
Wash the glycol terephthalate with water and dry it under vacuum.
Zana zinazohitajika:
Maji yaliyosafishwa kwa mvuke
Faneli ya Kioo Yenye Bomba
Karatasi ya Kuchuja
Pampu ya utupu3
3
Heat at 280 °C under nitrogen
Heat at 280 °C under nitrogen
Melt it and heat at 280 °C for 8½ hours in a slow stream of nitrogen: no air may reach it. It grows thick as it polymerises.
Zana zinazohitajika:
Chupa yenye chini cha mviringo
Sahani ya Kupasha Joto
Themokapo yenye kionyeshi
Silinda ya gesi ya naitrojeni
Glavu Zinazostahimili Joto
Miwani ya kinga dhidi ya kemikali4
4
Test for cold-drawing
Test for cold-drawing
Pull a thread from the melt with a rod and let it cool. It is ready when the cold thread can be stretched to several times its length. The finished polymer melts at 254–255 °C.
Zana zinazohitajika:
Fimbo ya Kioo ya Kukoroga
Glavu Zinazostahimili Joto5
5
Extrude and cut into chips
Extrude and cut into chips
Extrude the molten polymer, let it cool, and cut it into chips (pellets).
Zana zinazohitajika:
Kitoaji cha plastiki
Kitengeneza chembe
Glavu Zinazostahimili JotoVifaa
2- Kishikilia Nafasi
- 89 gKishikilia Nafasi
Zana Zinazohitajika
15- Kishikilia Nafasi
- Kishikilia Nafasi
- Kishikilia Nafasi
- Kishikilia Nafasi
- Kishikilia Nafasi
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- 1 vendor sell this, none ship to you yetKishikilia Nafasi
- Kishikilia Nafasi
- Kishikilia Nafasi
- Kishikilia Nafasi
- Kishikilia Nafasi
- Kishikilia Nafasi
- Kishikilia Nafasi
- Kishikilia Nafasi
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