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Plasticised PVC (Plastisol)
Charlie

Ṣẹ́dá nipasẹ̀

Charlie

22. Oṣù Kẹsàn 2026DE
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Plasticised PVC (Plastisol)

PVC was known for decades as a hard, brittle powder nobody could use. In 1926 Waldo Semon at B.F. Goodrich found that certain liquids dissolve it only when hot, and that the hot solution sets on cooling into a soft, rubber-like gel - flexible PVC. **US 1,929,453**, "Synthetic rubber-like composition and method of making same", Semon, assigned to B.F. Goodrich, granted 10. October 1933, claims dissolving "an insoluble polymerized vinyl halide at an elevated temperature" in a liquid that dissolves it only well above room temperature, and gelling it by cooling. One example: 8 parts PVC, 8 parts tricresyl phosphate, 3 parts dibutyl phthalate. **Plastisol is that idea in a bottle**: PVC grains suspended, undissolved, in plasticiser. Heat makes the liquid dissolve the grains and fuse into solid flexible PVC. You bake test films at three temperatures and pull them apart to find where it truly fuses.
Olùbẹ̀rẹ̀
2 hours

Ìlànà

1

Ventilate and set the oven

Use a toaster oven kept for crafts, never food, by an open window. Put the probe thermometer inside - dial settings are rarely accurate.

Àwọn irinṣẹ́ tí a nílò:

Ìléru orí tábìlìÌléru orí tábìlì
Ẹ̀rọ ìwọ̀n ooru oníhun tí ó dúró sí inúẸ̀rọ ìwọ̀n ooru oníhun tí ó dúró sí inú
Ìbòjú ìmí N95Ìbòjú ìmí N95
2

Stir the plastisol

The PVC grains settle. Stir the plastisol from the bottom for 2 minutes until even. Read the label's fusion temperature.

Àwọn ohun èlò fún ìgbésẹ̀ yìí:

PlastisolPlastisol150 ml

Àwọn irinṣẹ́ tí a nílò:

Ọ̀pá ÌrúwéỌ̀pá Ìrúwé
3

Spread three films

On the silicone mat, spread three 100 x 40 mm films about 1.5 mm thick with the palette knife.

Àwọn ohun èlò fún ìgbésẹ̀ yìí:

PlastisolPlastisol50 ml

Àwọn irinṣẹ́ tí a nílò:

Ẹní ìdáná siliconeẸní ìdáná silicone
Ìdìpọ̀ ọ̀bẹ paletiÌdìpọ̀ ọ̀bẹ paleti
Ìwọ̀n IrinÌwọ̀n Irin
4

Bake at three temperatures

Bake one film 10 minutes each at 130 °C, 150 °C and the label's fusion temperature (commonly 160–180 °C). Never exceed the label maximum.

Àwọn irinṣẹ́ tí a nílò:

Ìléru orí tábìlìÌléru orí tábìlì
Ẹ̀rọ Ìwọ̀n Ooru Infurarẹ́dìẸ̀rọ Ìwọ̀n Ooru Infurarẹ́dì
Ìbọ̀wọ́ wẹ́lídìnÌbọ̀wọ́ wẹ́lídìn
5

Cool and cut strips

Cool 10 minutes. Peel each film and cut a 10 mm strip from its centre. Mark its temperature.

Àwọn irinṣẹ́ tí a nílò:

Ọ̀bẹ iṣẹ́Ọ̀bẹ iṣẹ́
Ìwọ̀n IrinÌwọ̀n Irin
6

Stretch and pull

Clamp one end in the vise. Hook the spring scale to the other and pull slowly. Record the peak force and how it failed.

Àwọn irinṣẹ́ tí a nílò:

Ẹ̀rọ Ìwọ̀n Agbára (Òṣùwọ̀n Ìsúnkì)Ẹ̀rọ Ìwọ̀n Agbára (Òṣùwọ̀n Ìsúnkì)
Ìdìmú TábìlìÌdìmú Tábìlì
Gílásì Ààbò Tí Ó Mọ́Gílásì Ààbò Tí Ó Mọ́
7

Recipe, cure curve, siblings

Ń ṣí ìwé Jupyter…
8

History & Context

**What the patent specifies:** gelling PVC in high-boiling liquids such as tricresyl phosphate and dibutyl phthalate. **Modern build (derived):** a commercial plastisol; many now use phthalate-free plasticisers. Flexible PVC became cable insulation, shower curtains, hoses and flooring. Its limits: the plasticiser slowly migrates out, so old soft PVC stiffens and turns sticky; and overheated PVC yellows and releases hydrogen chloride, which is why the label's maximum temperature matters.

Àwọn ohun-èlò

1

Àwọn irinṣẹ́ tó nílò

13

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