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Polymer Gasoline: Propylene from Cracked Gas Polymerised over Phosphoric Acid (Gulf, US 3,071,535)
The propylene in a refinery's cracked gas can be joined into gasoline-sized molecules over a phosphoric acid catalyst. The result is an olefinic polymer gasoline of high research octane but high sensitivity, so Gulf blends it into regular grade only.
Result (Gulf's example, barrels per day): from 4,851 of C3 fractions, 1,645 of polymer gasoline; the propane and unreacted gas, 1,552 as fuel-oil equivalent, go to fuel.
Source: Condrasky & Glazier, US 3,071,535 (Gulf, filed 1959). Not given: temperature, pressure, reactor design. Liquefied gases under pressure: fire risk. Picture drawn by Youblob.
Ògbóǹtarìgì
1 day
Ìlànà
1
1
Collect the C3 streams
Collect the C3 streams
Gather the olefinic C3 fractions of the refinery: in Gulf's example 4,230 barrels a day from the catalytic cracker and 621 from the coker.
Àwọn ohun èlò fún ìgbésẹ̀ yìí:
Ìpín propane-propylene4851 parts by volumeÀwọn irinṣẹ́ tí a nílò:
Àgbá gáàsì tí a fi ìfúnpá kún
Pọ́ǹpù ìgbé omi2
2
Polymerise over phosphoric acid
Polymerise over phosphoric acid
Contact the C3 stream with a polymerisation catalyst such as phosphoric acid, which joins the propylene into olefinic polymer gasoline. Gulf gives no temperature or pressure. Ours: a solid phosphoric acid catalyst in a pressure reactor.
Àwọn irinṣẹ́ tí a nílò:
Amúyára ìhùwàsí phosphoric acid líle
Ìkòkò ìṣesí ìfúnpá
Ẹ̀rọ Ìwọ̀n Ìtẹ̀
Pirómítà3
3
Separate the polymer gasoline from the gas
Separate the polymer gasoline from the gas
Separate the liquid polymer gasoline (1,645) from the C3 gas left over (1,552 as fuel-oil equivalent), which is used as fuel. Ours: a fractionating still.
Àwọn irinṣẹ́ tí a nílò:
Ohun ìsun tí ó pín
Táńkì ìtọ́jú epo4
4
Keep it for regular grade
Keep it for regular grade
Because its octane sensitivity is rather high, the polymer gasoline is blended into regular-grade petrol, not premium.
Àwọn irinṣẹ́ tí a nílò:
Táńkì ìtọ́jú epoÀwọn ohun-èlò
1- 4851 parts by volumeÀyè
Àwọn irinṣẹ́ tó nílò
8- Àyè
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