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Neodymium Magnets, Sample 16: 53Fe-17B-30Nd Sintered (Sagawa 1988)
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Neodymium Magnets, Sample 16: 53Fe-17B-30Nd Sintered (Sagawa 1988)

Neodymium magnets are iron, boron and neodymium. Sagawa's team at Sumitomo melted the three together, ground the casting to a powder finer than 10 µm, lined the grains up in a magnetic field while pressing them, and sintered the compact in argon. This is their sample 16, 53 % iron, 17 % boron and 30 % neodymium by atoms: 4.2 MGOe. Source: M. Sagawa et al. (Sumitomo Special Metals), US 4,770,723 (1988). Unknown: how the pure iron, the ferroboron and the neodymium metal are made, and how the finished magnets are magnetised; the patent does not say. The 1 kg weights are our arithmetic from the patent's atomic percentages. Picture: the patent's Fig. 8.
Ògbóǹtarìgì
2 days

Ìlànà

1

Weigh sample 16: 53 Fe, 17 B, 30 Nd

Sample 16 is 53 % iron, 17 % boron and 30 % neodymium by atoms. Use 99.9 % electrolytic iron, ferroboron (19.38 % B, 5.32 % Al, 0.74 % Si, 0.03 % C, the rest iron) and neodymium of 99.7 % or better. Ours: a 1 kg melt, by arithmetic: 301.6 g iron, 126.9 g ferroboron, 579.2 g neodymium. Unknown: how these three are made.

Àwọn ohun èlò fún ìgbésẹ̀ yìí:

Irin elekitirolitikiIrin elekitirolitiki301.6 g
FerroboronFerroboron126.9 g
Irin neodymiumIrin neodymium579.2 g

Àwọn irinṣẹ́ tí a nílò:

Òǹwọ̀n ìdọ́gbaÒǹwọ̀n ìdọ́gba
2

Melt by high frequency in argon and cast

Melt the charge in a high-frequency (induction) furnace under argon and pour it into a water-cooled copper mould.

Àwọn irinṣẹ́ tí a nílò:

Ìléru inductionÌléru induction
Ìkòkò Amọ̀ Tí Ń Kojú InáÌkòkò Amọ̀ Tí Ń Kojú Iná
ArgonArgon
Àgbá gáàsì tí a fi ìfúnpá kúnÀgbá gáàsì tí a fi ìfúnpá kún
Mọ́ọ̀dù bàbà tí a fi omi tutùMọ́ọ̀dù bàbà tí a fi omi tutù
Ìbọ̀wọ́ Tí Ń Fara Da OoruÌbọ̀wọ́ Tí Ń Fara Da Ooru
3

Stamp to 35 mesh, ball-mill to 3-10 µm

Crush the casting in a stamp mill until it passes a 35-mesh sieve. Then grind it in a ball mill for 3 hours, to 3-10 µm.

Àwọn irinṣẹ́ tí a nílò:

Ẹ̀rọ Lílù ÒkútaẸ̀rọ Lílù Òkúta
Àkójọ ajọ̀ (ihò onípele)Àkójọ ajọ̀ (ihò onípele)
Ẹ̀rọ Lílọ Bọ́ọ̀lù IrinẸ̀rọ Lílọ Bọ́ọ̀lù Irin
Gíláàsì ààbòGíláàsì ààbò
4

Press in a 10 kOe field at 1.5 t/cm²

Line the powder up in a magnetic field of 10 kOe and press it at 1.5 tonnes per cm². Unknown: the size and shape of the magnets.

Àwọn irinṣẹ́ tí a nílò:

Ẹ̀rọ ìtẹ̀ pẹ̀lú pápá òòfàẸ̀rọ ìtẹ̀ pẹ̀lú pápá òòfà
5

Sinter in argon at 1000-1200 °C

Sinter the compacts at 1000-1200 °C for about one hour in argon, then let them cool. Sample 16 measured 4.5 kG remanence, 14.8 kOe coercivity and 4.2 MGOe.

Àwọn irinṣẹ́ tí a nílò:

Ààrò Ọ̀pọ́nÀàrò Ọ̀pọ́n
ArgonArgon
Àgbá gáàsì tí a fi ìfúnpá kúnÀgbá gáàsì tí a fi ìfúnpá kún
Ìbọ̀wọ́ Tí Ń Fara Da OoruÌbọ̀wọ́ Tí Ń Fara Da Ooru
6

Magnetise the magnets

Unknown: how the sintered magnets are magnetised. Sagawa measures them on a B-H tracer but gives no magnetising field or apparatus.

Àwọn irinṣẹ́ tí a nílò:

Ọ̀nà ìfòòfà tí a kò mọ̀Ọ̀nà ìfòòfà tí a kò mọ̀

Àwọn ohun-èlò

3

Àwọn irinṣẹ́ tó nílò

14

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