Pakikipagtulungan
SINING
BEAUTY AT WELLNESS
CRAFTS
KULTURA AT KASAYSAYAN
LIBANGAN
KAPALIGIRAN
PAGKAIN AT INUMIN
REVERSE ENGINEERING
AGHAM
ISPORTS
TEKNOLOHIYA
MGA WEARABLE
Youblob · CC0
Hydroxyl-Ended Silicone Oil: D4 Opened with Potash, Then Water (Ceyzeriat 1964)
A trace of hot potash opens the ring of D4 and strings it into a long, thick chain. Water added a little at a time then cuts the chains back and leaves hydroxyl groups on their ends, which is what later lets the oil cure into rubber. This is Louis Ceyzeriat's oil A, the base of every sealant in his patent: 21,000 centistokes, 0.15 % hydroxyl.
Source: L. Ceyzeriat (Rhône-Poulenc), US 3,133,891 (1964), column 4. His neutraliser was the precipitated silica Hi-Sil X303; we use our precipitated silica in its place. The potash mix and the equipment are ours. Picture drawn by Youblob.
Abantado
2 days
Mga Tagubilin
1
1
Make the 10 % potash
Make the 10 % potash
Dissolve 0.5 part of potassium hydroxide in 4.5 parts of water (our arithmetic for 5 parts of a 10 % solution). All parts are by weight.
Mga materyales para sa hakbang na ito:
Potassium hydroxide0.5 parts
Tubig4.5 partsMga kailangang kasangkapan:
Sisidlang salamin
Timbangang panimbang2
2
Heat D4 with the potash under nitrogen
Heat D4 with the potash under nitrogen
Heat 5000 parts of octamethylcyclotetrasiloxane (it melts at 17.5 °C) with the 5 parts of 10 % potash at 150 °C for 3½ hours under nitrogen. The oil thickens to 31,000 centistokes while hot.
Mga materyales para sa hakbang na ito:
Octamethylcyclotetrasiloxane (D4)5000 partsMga kailangang kasangkapan:
Prasko ng Salamin sa Distilasyon
Pang-init na Plato
Termometro
Panghalo
Silindro ng Nitrogen3
3
Add water a little at a time
Add water a little at a time
Still hot, add 16.5 parts of water in small portions over 3 hours 40 minutes. The hot oil thins to 1730 centistokes.
Mga materyales para sa hakbang na ito:
Tubig16.5 partsMga kailangang kasangkapan:
Prasko ng Salamin sa DistilasyonPang-init na PlatoTermometroPanghalo4
4
Cool, then neutralise with silica
Cool, then neutralise with silica
Let it cool for 15 hours. Then stir in 50 parts of precipitated silica to neutralise the potash. The liquid now measures 13,400 centistokes at 25 °C.
Mga materyales para sa hakbang na ito:
Precipitated silica50 partsMga kailangang kasangkapan:
Prasko ng Salamin sa DistilasyonPanghalo5
5
Strip the volatiles at 195–200 °C
Strip the volatiles at 195–200 °C
Heat it to about 195–200 °C in a current of nitrogen, with a water condenser on the outlet. 655 parts of liquid distil over; 4345 parts of oil A stay in the boiler, 21,000 centistokes at 25 °C with 0.15 % hydroxyl groups.
Mga kailangang kasangkapan:
Prasko ng Salamin sa Distilasyon
Ikid ng kondensadorPang-init na PlatoTermometroSilindro ng Nitrogen
Garapong Salamin na May TakipMga Materyales
4- 0.5 partsPlaceholder
- 21 partsPlaceholder
- 5000 partsPlaceholder
- 50 partsPlaceholder
Mga Kinakailangang Kasangkapan
9- Placeholder
- Placeholder
- Placeholder
- Placeholder
- Placeholder
- Placeholder
- Placeholder
- Placeholder
- Placeholder
Ang blueprint na ito ay gumagawa ng
Kaugnay na Blueprint
Ang mga blueprint na ito ay nagbabahagi ng kaalaman — mga teknik, materyales, o prinsipyo
CC0 Pampublikong Domain
Ang blueprint na ito ay inilabas sa ilalim ng CC0. Malaya kang kumopya, magbago, mamahagi, at gumamit nang walang pahintulot.
Suportahan ang Maker sa pamamagitan ng pagbili ng mga produkto sa kanilang Blueprint Komisyon ng Maker itinakda ng mga Vendor, o lumikha ng bagong bersyon ng Blueprint na ito at isama bilang koneksyon sa iyong Blueprint upang ibahagi ang kita.