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Colloidal Silver: Carey Lea's Soluble Silver from Silver Nitrate
Charlie

Yaremwe na

Charlie

19. Ukwakira 2026DE
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Colloidal Silver: Carey Lea's Soluble Silver from Silver Nitrate

Carey Lea found in 1891 that silver nitrate reduced by ferrous sulphate in the presence of sodium citrate gives a silver that dissolves in water with a deep red colour. The 1907 US Dispensatory gives the recipe: the mixed iron and citrate solutions poured into 10 % silver nitrate, the precipitate washed by redissolving it in water and throwing it down again with absolute alcohol. Dried, it is a bluish-green mass of about 97 % silver. Salt solutions precipitate it, so use distilled water only. The picture: our diagram.
Hagati
2 days

Amabwiriza

1

Make the three solutions

Dissolve 10 g of silver nitrate in distilled water to 100 ml (10 %). Separately dissolve 30 g of ferrous sulphate in 100 ml of water and 36 g of crystallised sodium citrate in 140 ml of water, then mix these two.

Ibikoresho by'iyi ntambwe:

Nitrate ya fezaNitrate ya feza10 g
Salfate y'icyumaSalfate y'icyuma30 g
Sitirate ya sodiyumuSitirate ya sodiyumu36 g
Amazi YatunganyijweAmazi Yatunganyijwe340 ml

Ibikoresho bikenewe:

Umunzani w'ibiroUmunzani w'ibiro
Igikoresho gipima ibitembaIgikoresho gipima ibitemba
Icupa ry'Ikirahure Rifite UmufunikoIcupa ry'Ikirahure Rifite Umufuniko
Akati k'Ikirahure ko KuvangaAkati k'Ikirahure ko Kuvanga
Uturindantoki twa NitirileUturindantoki twa Nitirile
2

Pour and stir

Pour the iron-citrate mixture into the silver nitrate solution, stirring all the time. A dark precipitate forms.

Ibikoresho bikenewe:

Akati k'Ikirahure ko KuvangaAkati k'Ikirahure ko Kuvanga
Icupa ry'Ikirahure Rifite UmufunikoIcupa ry'Ikirahure Rifite Umufuniko
Uturindantoki twa NitirileUturindantoki twa Nitirile
3

Settle and wash with alcohol

Let it settle and pour off the liquid. Dissolve the precipitate in a little distilled water and throw it down again with absolute alcohol. Pour off the alcohol.

Ibikoresho bikenewe:

Alukoro itunganyeAlukoro itunganye
Amazi YatunganyijweAmazi Yatunganyijwe
Icupa ry'Ikirahure Rifite UmufunikoIcupa ry'Ikirahure Rifite Umufuniko
Akati k'Ikirahure ko KuvangaAkati k'Ikirahure ko Kuvanga
4

Dry

Dry the precipitate in a dish at room temperature. It becomes a bluish or greenish mass.

Ibikoresho bikenewe:

Isahani yo kumishaIsahani yo kumisha
5

Make the 1 % solution

Dissolve the dried silver in distilled water at 1 g to 100 ml. It dissolves deep red. Keep it in a stoppered bottle and do not mix it with salt water.

Ibikoresho by'iyi ntambwe:

Amazi YatunganyijweAmazi Yatunganyijwe500 ml

Ibikoresho bikenewe:

Umunzani w'ibiroUmunzani w'ibiro
Amacupa y'ikirahuri afite ibipfundikizoAmacupa y'ikirahuri afite ibipfundikizo

Ibikoresho

4

Ibikoresho bikenewe

9

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