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Polypropylene Pellets by Bulk Polymerisation in Liquid Propylene
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Charlie

17. Ukwakira 2026DE
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Polypropylene Pellets by Bulk Polymerisation in Liquid Propylene

Polypropylene is propylene strung into long chains. In the bulk process the propylene itself is the liquid: kept liquid at 30–40 atm, it polymerises at 60–80 °C on a catalyst of titanium tetrachloride on magnesium chloride. Letting the pressure down boils off the unreacted propylene and leaves a powder, which is extruded into pellets. Natta found the regular (isotactic) form in 1954. The picture: our diagram of reactor, flash and pelletiser.
Hejuru
Continuous

Amabwiriza

1

Polymerise in liquid propylene

Feed propylene and the TiCl4-on-MgCl2 catalyst into the reactor. Hold it at 30–40 atm so the propylene stays liquid, at 60–80 °C.

Ibikoresho by'iyi ntambwe:

PropilenePropilene1 t

Ibikoresho bikenewe:

Reyakitori y'igitutuReyakitori y'igitutu
Igitera-vuba cya Ziegler-Natta (TiCl4 kuri MgCl2)Igitera-vuba cya Ziegler-Natta (TiCl4 kuri MgCl2)
Igikandamiza gaziIgikandamiza gazi
2

Let the pressure down

Release the pressure: the unreacted propylene boils off and the polymer is left as a fine powder. Compress the propylene and return it.

Ibikoresho bikenewe:

Igikandamiza gaziIgikandamiza gazi
3

Pelletise

Melt the powder in the extruder, with any additives the grade needs, and cut the strand into pellets.

Ibikoresho bikenewe:

Imashini isohora pulasitikiImashini isohora pulasitiki
4

Pressure units

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Ibikoresho

1
  • Umwanya

Ibikoresho bikenewe

4

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