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Iso-hexanes and Isopentane: Light Straight-Run Gasoline Isomerised over Platinum-Alumina with Hydrogen (Gulf, US 3,071,535)
The lightest straight-run gasoline is mostly straight-chain pentane and hexane, of low octane. Rearranged into their branched forms over a platinum catalyst with hydrogen, they become isopentane and iso-hexanes, high in both research and motor octane.
Result (Gulf's example, barrels per day): from 7,549 of light straight-run gasoline, 2,873 of isopentane and 2,792 of iso-hexanes, plus 1,796 of isoheptanes split off beforehand.
Source: Condrasky & Glazier, US 3,071,535 (Gulf, filed 1959). Not given: temperature, pressure, space velocity. Hydrogen and light hydrocarbons: fire risk. Picture drawn by Youblob.
Uzman
1 day
Talimatlar
1
1
Split off the isoheptanes
Split off the isoheptanes
Prefractionate the light straight-run gasoline (C5-190 °F, 7,549 barrels a day) to separate isoheptanes and heavier, 1,796, which go to hydrogen treating, from the C5-C6 paraffins.
Bu adım için malzemeler:
Hafif düz damıtım benzini7549 parts by volumeGerekli aletler:
Fraksiyonlu imbik
Petrol depolama tankı2
2
Split the C5-C6 into pentane and hexane cuts
Split the C5-C6 into pentane and hexane cuts
Distil the C5-C6 fraction into a concentrated normal-pentane cut and a cut concentrated in normal hexane and methylpentanes.
Gerekli aletler:
Fraksiyonlu imbik3
3
Isomerise each cut over platinum-alumina with hydrogen
Isomerise each cut over platinum-alumina with hydrogen
Isomerise the two cuts separately over a halogen-promoted platinum-alumina catalyst with hydrogen. Gulf uses off-gas from its platinum reformer, 360,000 cubic feet a day. Gulf gives no temperature or pressure.
Gerekli aletler:
Platin Reform Katalizörü
Sabit yataklı borulu reaktör
Hidrojen
Basınç Göstergesi
Pirometre4
4
Fractionate and recycle the unconverted
Fractionate and recycle the unconverted
Fractionate the reactor effluent. Send unconverted normal pentane, normal hexane and methylpentanes back to the reactors. Keep the isopentane (2,873) and iso-hexanes (2,792) for blending; 156 goes to fuel gas.
Gerekli aletler:
Fraksiyonlu imbik
Petrol depolama tankıMalzemeler
1- 7549 parts by volumeYer Tutucu
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Planı üzerinden ürün satın alarak Maker'ı destekleyin, böylece Maker Komisyonu Satıcılar tarafından belirlenen komisyonu kazanırlar veya bu Planın yeni bir versiyonunu oluşturun ve gelir paylaşımı için kendi Planınıza bağlantı olarak ekleyin.


