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Barium-Calcium Ferrite Disc Magnet: Part of the Barium Replaced by Calcium (Went, Philips 1956, Ex. 21)
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Barium-Calcium Ferrite Disc Magnet: Part of the Barium Replaced by Calcium (Went, Philips 1956, Ex. 21)

A ceramic magnet in which part of the barium is replaced by calcium: 0.06 mol barium carbonate and 0.04 mol calcium carbonate to 0.6 mol iron oxide, milled, fired in oxygen, milled again, pressed and passed quickly through a hot furnace. Went's rod held 1,660 gauss with a coercive force of 1,210 oersted. Source: J. J. Went, G. W. van Oosterhout and E. W. Gorter (Philips), US 2,762,777 (1956), Example 21. They sintered rods; discs and the magnetising are ours. Picture: ferrite magnets, Omegatron, Wikimedia Commons, CC BY-SA 3.0.
Osezingeni eliphezulu
2 days

Imiyalelo

1

Weigh barium carbonate, chalk and iron oxide

Weigh 11.84 g barium carbonate (0.06 mol), 4.004 g calcium carbonate (0.04 mol) and 99.55 g ferric oxide (0.6 mol). Barium carbonate is poisonous if swallowed: gloves and a dust respirator.

Izinto zokwakha zalesi sinyathelo:

I-barium carbonate (i-witherite)I-barium carbonate (i-witherite)11.84 g
I-calcium carbonate (umcako omhlophe)I-calcium carbonate (umcako omhlophe)4.004 g
I-ferric oxideI-ferric oxide99.55 g

Amathuluzi adingekayo:

Isikali sesilinganisoIsikali sesilinganiso
Amagilavu erabhaAmagilavu erabha
Isivikelo Sokuphefumula i-P100Isivikelo Sokuphefumula i-P100
2

Mill with alcohol 4 hours and dry

Grind the mixture with alcohol in a ball mill for 4 hours, then dry it.

Amathuluzi adingekayo:

Umshini Wokugaya Ngamabhola EnsimbiUmshini Wokugaya Ngamabhola Ensimbi
I-ethanol - izinga lelabhorethri, 95 %I-ethanol - izinga lelabhorethri, 95 %
Ihhavini yokomisaIhhavini yokomisa
3

Presinter in oxygen at 1000 °C for 2 hours

Fire the dry powder in oxygen at 1000 °C for 2 hours (ours: a tube furnace fed from an oxygen cylinder).

Amathuluzi adingekayo:

Isithando SepayipiIsithando Sepayipi
I-oxygenI-oxygen
Isilinda segesi ecindezelweIsilinda segesi ecindezelwe
Amagilavu Amelana NokushisaAmagilavu Amelana Nokushisa
4

Mill again 4 hours, dry, press at 1.5 t/cm²

Grind with alcohol in the ball mill for 4 hours, dry, and press at 1.5 tonnes per cm² (ours: discs instead of rods).

Amathuluzi adingekayo:

Umshini Wokugaya Ngamabhola EnsimbiUmshini Wokugaya Ngamabhola Ensimbi
I-ethanol - izinga lelabhorethri, 95 %I-ethanol - izinga lelabhorethri, 95 %
Ihhavini yokomisaIhhavini yokomisa
Umshini wokucindezela we-hydraulicUmshini wokucindezela we-hydraulic
Isikhunta sokucindezela idiskiIsikhunta sokucindezela idiski
5

Pass through a 1200 °C zone in 10 minutes

Sinter at 1200 °C by passing the pieces through a 10 cm hot zone at 10 mm per minute, which is 10 minutes in the heat.

Amathuluzi adingekayo:

Isithando SepayipiIsithando Sepayipi
Amagilavu Amelana NokushisaAmagilavu Amelana Nokushisa
6

Magnetise the discs

The patent gives no magnetising method. Ours: lay a disc with its faces against the poles of a strong electromagnet, switch the current on, then off. Find which face is north with a compass.

Amathuluzi adingekayo:

I-electromagnetI-electromagnet
IkhompasiIkhompasi

Izinto

3

Amathuluzi Adingekayo

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