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Hydrogen Peroxide 3 %: Barium Peroxide in Dilute Sulphuric Acid
Thénard first made hydrogen peroxide from barium peroxide; the improved way stirs the peroxide into sulphuric acid, which takes the barium out as insoluble barium sulphate. Titrate the clear liquid with permanganate to find its strength, dilute it to 3 %, the mild antiseptic and bleach, and keep it in a dark bottle. Even 3 % hurts the eyes.
The picture: our diagram of the four stages.
Osezingeni eliphezulu
A day
Imiyalelo
1
1
Peroxide into cold acid
Peroxide into cold acid
Grind the barium peroxide to a paste with a little cold water. Stand a beaker of dilute sulphuric acid in ice and stir the paste in a little at a time. Stop while a drop of the liquid still turns blue litmus red: it keeps better slightly acid.
Izinto zokwakha zalesi sinyathelo:
I-barium peroxide150 g
I-asidi ye-sulfuric ehlanjululwe1 ilithaAmathuluzi adingekayo:
Isigqulo Nomgqulo
Isikali sesilinganiso
Ibhikha Le-borosilicate
Ibhodwe Elikhulu
Amaqhwa aqoshiwe
Induku Yengilazi Yokugovuza
Iphepha le-litmus
Izibuko Zokuchitheka Kwamakhemikhali
Amagilavu erabha2
2
Filter
Filter
Let the white barium sulphate settle and filter it off. The clear liquid is hydrogen peroxide in water.
Amathuluzi adingekayo:
Ifanela Lengilazi Elinomlomo
Iphepha Lokuhluza
Ibhikha Le-borosilicate
Izibuko Zokuchitheka Kwamakhemikhali
Amagilavu erabha3
3
Titrate a sample
Titrate a sample
Dissolve 3.161 g of permanganate to 1 litre in a volumetric flask. Pipette 1 mL of the peroxide into a flask with some dilute sulphuric acid and run permanganate in from the burette until the first lasting pink. Note the reading (step 5).
Amathuluzi adingekayo:
I-potassium permanganate — KMnO4
Ibhodlela levolumu
I-pipette enemigqa yokukala (i-Mohr)
Ibhodlela le-Erlenmeyer
I-burette (ingilazi)
Isibambi sasilabhorethri (i-burette/ibhodlela)
I-asidi ye-sulfuric ehlanjululwe
Izibuko Zokuchitheka Kwamakhemikhali
Amagilavu erabha4
4
Dilute and bottle
Dilute and bottle
Weigh the batch, stir in the distilled water the notebook gives, and keep it cool in a dark, closed bottle.
Izinto zokwakha zalesi sinyathelo:
Amanzi Acwengisisiwe0.1 ilithaAmathuluzi adingekayo:
Isikali sesilinganiso
Induku Yengilazi Yokugovuza
Ibhodlela lengilazi ye-amber
Izibuko Zokuchitheka Kwamakhemikhali
Amagilavu erabha5
5
Strength and dilution
Strength and dilution
Ilayisha incwadi ye-Jupyter…
Izinto
3- 150 gIsibambeli
- 1 ilithaIsibambeli
- 0.1 ilithaIsibambeli
Amathuluzi Adingekayo
19- Isibambeli
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