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Metal Oxide Varistor: Zinc Oxide with 1 % Aluminium Oxide, Bismuth Oxide Paste Fired On (Masuyama 1972, Ex. 5)
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28. uMfumfu 2026FI
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Metal Oxide Varistor: Zinc Oxide with 1 % Aluminium Oxide, Bismuth Oxide Paste Fired On (Masuyama 1972, Ex. 5)

A varistor with bismuth oxide fired on from a paste instead of mixed in: 99 % zinc oxide with 1 % aluminium oxide by moles, sintered at 1350 °C, coated with bismuth oxide paste and fired at 800 °C. The disc measured a C-value of 6.2 at 1 mA and a nonlinearity exponent n of 7.4. Source: T. Masuyama, M. Matsuoka and T. Nishi (Matsushita), US 3,663,458 (1972), Example 5. Unknown: what the silver paint is, and how strong the epoxy solution of the paste is. The spraying is ours, after US Army Corps of Engineers EM 1110-2-3401 (1999). The 10 g batch is our arithmetic. Picture: the patent's drawing.
Osezingeni eliphezulu
2 days

Imiyalelo

1

Weigh 99 : 1 and wet-mill 5 hours

Mix zinc oxide and aluminium oxide 99 : 1 by moles. Ours, for 10 g: 9.875 g zinc oxide and 0.125 g aluminium oxide (our arithmetic). Mill wet for 5 hours, then dry, as in Example 1. Unknown: the milling liquid.

Izinto zokwakha zalesi sinyathelo:

Impuphu Ye-Zinc OxideImpuphu Ye-Zinc Oxide9.875 g
Impuphu ye-alumina (i-aluminium oxide)Impuphu ye-alumina (i-aluminium oxide)0.125 g

Amathuluzi adingekayo:

Isikali sesilinganisoIsikali sesilinganiso
Umshini Wokugaya Ngamabhola EnsimbiUmshini Wokugaya Ngamabhola Ensimbi
Ihhavini yokomisaIhhavini yokomisa
2

Press discs 13 mm by 2.5 mm

Press discs 13 mm across and 2.5 mm thick at 340 kg/cm², as in Example 1.

Amathuluzi adingekayo:

Umshini wokucindezela we-hydraulicUmshini wokucindezela we-hydraulic
Isikhunta sokucindezela idiskiIsikhunta sokucindezela idiski
I-Vernier CaliperI-Vernier Caliper
3

Sinter 1 hour at 1350 °C and furnace-cool

As in Example 2: sinter in air at 1350 °C for 1 hour and let the discs cool in the furnace.

Amathuluzi adingekayo:

Isithando se-muffleIsithando se-muffle
4

Lap both faces

Lap both faces with silicon carbide abrasive. Example 5 gives no thickness.

Amathuluzi adingekayo:

Amagcubu e-silicon carbideAmagcubu e-silicon carbide
I-Vernier CaliperI-Vernier Caliper
5

Coat with bismuth oxide paste and fire at 800 °C

Coat both lapped faces with a paste of 50 % by weight bismuth oxide in a solution of epoxy resin in butyl alcohol, and fire it in air at 800 °C for 30 minutes. The bismuth oxide diffuses into the zinc oxide. Not given: how much paste, or the strength of the epoxy solution.

Izinto zokwakha zalesi sinyathelo:

I-bismuth oxideI-bismuth oxide1 as required

Amathuluzi adingekayo:

I-epoxy resinI-epoxy resin
I-n-ButanolI-n-Butanol
Isithando se-muffleIsithando se-muffle
6

Spray aluminium electrodes and attach leads

Spray a metallised film of aluminium on both faces. Attach a lead wire to each with conductive silver paint, as in Example 1. Ours, after US Army Corps of Engineers EM 1110-2-3401 (1999): wire-arc spray the aluminium from two 3.2 mm wires melted by an 18-40 V DC arc and atomised by compressed air, 15-20 cm from the disc and never at less than 45°, in at least two coats at right angles of 50-75 µm each. Unknown: the paint.

Izinto zokwakha zalesi sinyathelo:

Isigaxa se-aluminiumIsigaxa se-aluminium1 as 3.2 mm spray wire
Upende wesiliva odlulisa ugesiUpende wesiliva odlulisa ugesi1 as required
Ucingo LwethusiUcingo Lwethusi2 izicucu

Amathuluzi adingekayo:

I-Vernier CaliperI-Vernier Caliper
Isibhamu sokufafaza nge-arc yocingoIsibhamu sokufafaza nge-arc yocingo
Umcindezeli womoya wezimboniUmcindezeli womoya wezimboni

Izinto

6

Amathuluzi Adingekayo

12

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