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Chemical-Resistant Gloves: Butyl Latex over Natural Rubber on a Cotton Liner (Hart & Collyer, US 4,190,685, 1980)
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Chemical-Resistant Gloves: Butyl Latex over Natural Rubber on a Cotton Liner (Hart & Collyer, US 4,190,685, 1980)

Dipped rubber gloves built in layers on a knitted cotton liner: one coat of natural rubber, then five coats of butyl rubber, which lets very little liquid or vapour through. Each coat is dipped from latex on a porcelain hand form, and the whole glove is cured under steam and air pressure. Made in Canada to protect soldiers against chemical warfare agents; worn gloves showed no penetration in 24 hours of field use. Result: flexible, soft chemical-resistant gloves with a comfortable cotton lining. Source: J. A. Hart and J. C. Collyer, US 4,190,685 (1980), latex method. Unknown: sizes, the pigments. Picture: the patent drawing.
Hejuru
Unknown

Amabwiriza

1

Sew the cotton liner

Cut knitted or interlock cotton fabric to a glove shape and sew it into a glove. It stretches both ways, soaks up sweat and makes the glove easy to put on and take off. Not given: sizes, the knit.

Ibikoresho by'iyi ntambwe:

Igitambaro cy’ipamba kiboshyweIgitambaro cy’ipamba kiboshywe1 liner

Ibikoresho bikenewe:

UmukasiUmukasi
Imashini yo kudodaImashini yo kudoda
Ingano zitazwiIngano zitazwi
2

Dip in coagulant

Pull the liner onto a porcelain hand form and flame it to smooth off the surface. Dip it in a 10 % solution of acetic acid in acetone, then turn the form for about 2½ minutes at 24 °C until it is dry. The coagulant sets the latex before it can soak through the cloth.

Ibikoresho by'iyi ntambwe:

Asidi asetike (isukuye cyane)Asidi asetike (isukuye cyane)1 10 % in acetone
AsetoneAsetone1 solvent

Ibikoresho bikenewe:

Ikibumbiro cy'agarindantokiIkibumbiro cy'agarindantoki
Itara rya PropaneItara rya Propane
3

Dip the natural rubber coat

Dip the liner into natural rubber latex (the patent uses LOTOL 1185) and leave it 5 seconds. Draw it out, turn it upside down and let it dry. Scrub the rubber film with an abrasive cleaner, a brush and water, and dry it again.

Ibikoresho by'iyi ntambwe:

Umupira w'igiti karemanoUmupira w'igiti karemano1 bath
Isabune isharuraIsabune isharura1 as needed

Ibikoresho bikenewe:

Ikibumbiro cy'agarindantokiIkibumbiro cy'agarindantoki
Uburoso bwo gukuburaUburoso bwo gukubura
4

Mix the butyl latex bath

Mix, in parts by dry weight: butyl rubber latex 100, sulphur 3, zinc dibutyldithiocarbamate 4, zinc oxide 5, formaldehyde 0.1 as a preservative, a liquid dithiocarbamate curing accelerator 4 (Merac 255 in the patent), and 6.5 of pigments (olive drab in the patent). Not given: the pigments.

Ibikoresho by'iyi ntambwe:

Latex ya rubber ya butylLatex ya rubber ya butyl100 parts dry
SufureSufure3 parts
Zinc dibutyldithiocarbamateZinc dibutyldithiocarbamate4 parts
Ifu ya oxide ya zinkiIfu ya oxide ya zinki5 parts
Umuti wa fomaledehide (fomaline 37 %)Umuti wa fomaledehide (fomaline 37 %)0.1 parts formaldehyde
Icyihutisha cya dithiocarbamate gisukikaIcyihutisha cya dithiocarbamate gisukika4 parts
Ibikoresho bitazwiIbikoresho bitazwi6.5 parts pigment

Ibikoresho bikenewe:

Igikoresho cyo kuvangaIgikoresho cyo kuvanga
5

Dip five butyl coats

Dip the glove into the butyl latex and draw it out at 10 cm per minute. At once turn the form at about 8 rpm at 24 °C until the film has gelled, then dry it upside down in an oven at 66 °C for 1 hour. Wash, dip and dry again until there are five butyl coats; do not use the abrasive cleaner on the butyl film.

Ibikoresho bikenewe:

Ikibumbiro cy'agarindantokiIkibumbiro cy'agarindantoki
Ifuru yo kumishahoIfuru yo kumishaho
6

Cure and finish

Dry the glove at 66 °C for 1 hour. Cure it for 3 hours in a pressure vessel with 30 psi steam in the jacket (131 °C) and 26 psi air in the chamber. Strip the gloves from the forms while hot; when cool, trim them and wash them in soapy water.

Ibikoresho by'iyi ntambwe:

IsabuneIsabune1 as needed

Ibikoresho bikenewe:

Otokilave yo ku mezaOtokilave yo ku meza
UmukasiUmukasi

Ibikoresho

13

Ibikoresho bikenewe

9

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