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Potassium Permanganate: Pyrolusite Fused with Caustic Potash, Turned Purple by Carbonic Acid
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Charlie

14. Ukwakira 2026DE
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Potassium Permanganate: Pyrolusite Fused with Caustic Potash, Turned Purple by Carbonic Acid

Glauber fused pyrolusite with potash in 1659 and watched the solution turn from green to violet to red: the chemical chameleon. Fuse the ore with caustic potash and saltpetre to green potassium manganate, then bubble carbonic acid through its solution to make purple permanganate. It is a strong oxidiser: keep it away from paper, wood and oil. The picture: potassium permanganate crystals.
Hejuru
Two days

Amabwiriza

1

Grind and weigh

Grind the pyrolusite fine and sift it. Weigh out caustic potash and saltpetre for it (step 6).

Ibikoresho by'iyi ntambwe:

Amabuye ya piroluzite (diokside ya manganeze)Amabuye ya piroluzite (diokside ya manganeze)100 g
Idorokiside ya potasiyumuIdorokiside ya potasiyumu130 g

Ibikoresho bikenewe:

Nitarate ya potasiyumu (nitiri)Nitarate ya potasiyumu (nitiri)
Isekuru n'UmuhiniIsekuru n'Umuhini
Akayunguruzo Gafite Urukoma RutoAkayunguruzo Gafite Urukoma Ruto
Umunzani w'ibiroUmunzani w'ibiro
Amadarubindi yo Kwirinda IbinyabutabireAmadarubindi yo Kwirinda Ibinyabutabire
Uturindantoki tw'ikawusuUturindantoki tw'ikawusu
2

Fuse

Melt the caustic potash in an iron crucible in the furnace and stir in the ore and saltpetre a little at a time with an iron rod. Keep it hot, stirring, until the mass is dark green. Lift it out and let it cool.

Ibikoresho bikenewe:

Akabindi k'icyumaAkabindi k'icyuma
Itanura ry'amakaraItanura ry'amakara
AmakaraAmakara
Uruti rw'icyumaUruti rw'icyuma
Amakoro y'Icyombo GishongeshaAmakoro y'Icyombo Gishongesha
Uturindantoki two gukomeza ibyumaUturindantoki two gukomeza ibyuma
Amadarubindi yo Kwirinda IbinyabutabireAmadarubindi yo Kwirinda Ibinyabutabire
3

Dissolve the green salt

Break up the cold melt and dissolve it in water. The solution is green.

Ibikoresho by'iyi ntambwe:

Amazi YatunganyijweAmazi Yatunganyijwe1 litiro

Ibikoresho bikenewe:

Igikombe cya BorosilikateIgikombe cya Borosilikate
Akati k'Ikirahure ko KuvangaAkati k'Ikirahure ko Kuvanga
Amadarubindi yo Kwirinda IbinyabutabireAmadarubindi yo Kwirinda Ibinyabutabire
Uturindantoki tw'ikawusuUturindantoki tw'ikawusu
4

Turn it purple

Bubble carbon dioxide through the solution from a glass tube until it turns deep purple and brown manganese dioxide settles out.

Ibikoresho bikenewe:

Gaze ya dioxyde de carboneGaze ya dioxyde de carbone
Agafuka k'imiyoboro y'ikirahureAgafuka k'imiyoboro y'ikirahure
Igikombe cya BorosilikateIgikombe cya Borosilikate
Amadarubindi yo Kwirinda IbinyabutabireAmadarubindi yo Kwirinda Ibinyabutabire
Uturindantoki tw'ikawusuUturindantoki tw'ikawusu
5

Crystallise

Let the brown sludge settle and pour the clear purple liquid off it; do not filter through paper, which it attacks. Evaporate on the sand bath until crystals form on cooling. Drain the dark purple needles and keep them in a closed glass jar.

Ibikoresho bikenewe:

Isahani yo kumishaIsahani yo kumisha
Isahani y'umucangaIsahani y'umucanga
Icupa ry'IkirahureIcupa ry'Ikirahure
Amadarubindi yo Kwirinda IbinyabutabireAmadarubindi yo Kwirinda Ibinyabutabire
Uturindantoki tw'ikawusuUturindantoki tw'ikawusu
6

Charge and yield

Gupakira ikaye ya Jupyter…

Ibikoresho

3

Ibikoresho bikenewe

19

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