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Potassium Permanganate: Pyrolusite Fused with Caustic Potash, Turned Purple by Carbonic Acid
Glauber fused pyrolusite with potash in 1659 and watched the solution turn from green to violet to red: the chemical chameleon. Fuse the ore with caustic potash and saltpetre to green potassium manganate, then bubble carbonic acid through its solution to make purple permanganate. It is a strong oxidiser: keep it away from paper, wood and oil.
The picture: potassium permanganate crystals.
Hejuru
Two days
Amabwiriza
1
1
Grind and weigh
Grind and weigh
Grind the pyrolusite fine and sift it. Weigh out caustic potash and saltpetre for it (step 6).
Ibikoresho by'iyi ntambwe:
Amabuye ya piroluzite (diokside ya manganeze)100 g
Idorokiside ya potasiyumu130 gIbikoresho bikenewe:
Nitarate ya potasiyumu (nitiri)
Isekuru n'Umuhini
Akayunguruzo Gafite Urukoma Ruto
Umunzani w'ibiro
Amadarubindi yo Kwirinda Ibinyabutabire
Uturindantoki tw'ikawusu2
2
Fuse
Fuse
Melt the caustic potash in an iron crucible in the furnace and stir in the ore and saltpetre a little at a time with an iron rod. Keep it hot, stirring, until the mass is dark green. Lift it out and let it cool.
Ibikoresho bikenewe:
Akabindi k'icyuma
Itanura ry'amakara
Amakara
Uruti rw'icyuma
Amakoro y'Icyombo Gishongesha
Uturindantoki two gukomeza ibyuma
Amadarubindi yo Kwirinda Ibinyabutabire3
3
Dissolve the green salt
Dissolve the green salt
Break up the cold melt and dissolve it in water. The solution is green.
Ibikoresho by'iyi ntambwe:
Amazi Yatunganyijwe1 litiroIbikoresho bikenewe:
Igikombe cya Borosilikate
Akati k'Ikirahure ko Kuvanga
Amadarubindi yo Kwirinda Ibinyabutabire
Uturindantoki tw'ikawusu4
4
Turn it purple
Turn it purple
Bubble carbon dioxide through the solution from a glass tube until it turns deep purple and brown manganese dioxide settles out.
Ibikoresho bikenewe:
Gaze ya dioxyde de carbone
Agafuka k'imiyoboro y'ikirahure
Igikombe cya Borosilikate
Amadarubindi yo Kwirinda Ibinyabutabire
Uturindantoki tw'ikawusu5
5
Crystallise
Crystallise
Let the brown sludge settle and pour the clear purple liquid off it; do not filter through paper, which it attacks. Evaporate on the sand bath until crystals form on cooling. Drain the dark purple needles and keep them in a closed glass jar.
Ibikoresho bikenewe:
Isahani yo kumisha
Isahani y'umucanga
Icupa ry'Ikirahure
Amadarubindi yo Kwirinda Ibinyabutabire
Uturindantoki tw'ikawusu6
6
Charge and yield
Charge and yield
Gupakira ikaye ya Jupyter…
Ibikoresho
3- Umwanya
- Umwanya
- 1 litiroUmwanya
Ibikoresho bikenewe
19- Umwanya
- Umwanya
- Umwanya
- Umwanya
- Umwanya
- Umwanya
- Umwanya
- Umwanya
- Umwanya
- Umwanya
- Umwanya
- Umwanya
- Umwanya
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