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Hydrogen Peroxide 3 %: Barium Peroxide in Dilute Sulphuric Acid
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Charlie

Created by

Charlie

14. October 2026DE
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Hydrogen Peroxide 3 %: Barium Peroxide in Dilute Sulphuric Acid

Thénard first made hydrogen peroxide from barium peroxide; the improved way stirs the peroxide into sulphuric acid, which takes the barium out as insoluble barium sulphate. Titrate the clear liquid with permanganate to find its strength, dilute it to 3 %, the mild antiseptic and bleach, and keep it in a dark bottle. Even 3 % hurts the eyes. The picture: our diagram of the four stages.
Advanced
A day

Instructions

1

Peroxide into cold acid

Grind the barium peroxide to a paste with a little cold water. Stand a beaker of dilute sulphuric acid in ice and stir the paste in a little at a time. Stop while a drop of the liquid still turns blue litmus red: it keeps better slightly acid.

Materials for this step:

Barium PeroxideBarium Peroxide150 g
Dilute Sulfuric AcidDilute Sulfuric Acid1 liter

Tools needed:

Mortar and PestleMortar and Pestle
Balance ScaleBalance Scale
Borosilicate BeakerBorosilicate Beaker
Large Cooking PotLarge Cooking Pot
Ice CubesIce Cubes
Glass Stirring RodGlass Stirring Rod
Litmus PaperLitmus Paper
Chemical Splash GogglesChemical Splash Goggles
Rubber GlovesRubber Gloves
2

Filter

Let the white barium sulphate settle and filter it off. The clear liquid is hydrogen peroxide in water.

Tools needed:

Glass Funnel - StemmedGlass Funnel - Stemmed
Filter PaperFilter Paper
Borosilicate BeakerBorosilicate Beaker
Chemical Splash GogglesChemical Splash Goggles
Rubber GlovesRubber Gloves
3

Titrate a sample

Dissolve 3.161 g of permanganate to 1 litre in a volumetric flask. Pipette 1 mL of the peroxide into a flask with some dilute sulphuric acid and run permanganate in from the burette until the first lasting pink. Note the reading (step 5).

Tools needed:

Potassium Permanganate - KMnO₄Potassium Permanganate - KMnO₄
Volumetric FlaskVolumetric Flask
Graduated Pipette (Mohr)Graduated Pipette (Mohr)
Erlenmeyer FlaskErlenmeyer Flask
Burette (Glass)Burette (Glass)
Utility Clamp (Burette/Flask)Utility Clamp (Burette/Flask)
Dilute Sulfuric AcidDilute Sulfuric Acid
Chemical Splash GogglesChemical Splash Goggles
Rubber GlovesRubber Gloves
4

Dilute and bottle

Weigh the batch, stir in the distilled water the notebook gives, and keep it cool in a dark, closed bottle.

Materials for this step:

Distilled WaterDistilled Water0.1 liter

Tools needed:

Balance ScaleBalance Scale
Glass Stirring RodGlass Stirring Rod
Amber Glass BottleAmber Glass Bottle
Chemical Splash GogglesChemical Splash Goggles
Rubber GlovesRubber Gloves
5

Strength and dilution

Loading Jupyter Notebook...

Materials

3

Tools Required

19

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